作者机构：
College of Science, Hunan Province Key Laboratory of Materials Surface & Interface Science and Technology, Central South University of Forestry and Technology, Changsha , Hunan, China;College of Science, Jiujiang University, Jiujiang , Jiangxi, China;[Mengdong He; Yuxiang Peng; Wei Li; Jianbo Li; Peihao Su; Exian Liu; Kaijun Wang] College of Science, Hunan Province Key Laboratory of Materials Surface & Interface Science and Technology, Central South University of Forestry and Technology, Changsha , Hunan, China;[Jianqiang Liu] College of Science, Jiujiang University, Jiujiang , Jiangxi, China
摘要：
The immunity of topological states against backscattering and structural defects provides them with a unique advantage in the exploration and design of high-precision low-loss optical devices. However, the operating bandwidth of the topological states in certain photonic structures is difficult to actively tune and flexibly reconfigure. In this study, we propose a valley topological photonic crystal (TPC) comprising two inverse honeycomb photonic crystals, consisting of hexagonal silicon and Ge2Sb2Te5 (GST) rods. When GST transitions from the amorphous phase to the crystalline phase, the edge band of the TPC appears as a significant redshift and is inversed from a"∪"to an"∩"shape with topological phase transition, which enables active tuning of the operating bandwidth and propagation direction of topological edge states. Both the topological edge and corner states in a triangular structure constructed using TPCs can be simultaneously adjusted and reconfigured via GST phase transition, along with a change in the group number of corner states. Using the adjustability of topological edge states and electromagnetic coupling between two different topological bearded interfaces, we develop a multichannel optical router with a high tuning degree of freedom, where channels can be actively reconfigured and their on/off states can be freely switched. Our study provides a strategy for the active regulation of topological states and may be beneficial for the development of reconfigurable topological optical devices. The immunity of topological states against backscattering and structural defects provides them with a unique advantage in the exploration and design of high-precision low-loss optical devices. However, the operating bandwidth of the topological states in certain photonic structures is difficult to actively tune and flexibly reconfigure. In this study, we propose a valley topological photonic crystal (TPC) comprising two inverse honeycomb photonic crystals, consisting of hexagonal silicon and Ge2Sb2Te5 (GST) rods. When GST transitions from the amorphous phase to the crystalline phase, the edge band of the TPC appears as a significant redshift and is inversed from a"∪"to an"∩"shape with topological phase transition, which enables active tuning of the operating bandwidth and propagation direction of topological edge states. Both the topological edge and corner states in a triangular structure constructed using TPCs can be simultaneously adjusted and reconfigured via GST phase transition, along with a change in the group number of corner states. Using the adjustability of topological edge states and electromagnetic coupling between two different topological bearded interfaces, we develop a multichannel optical router with a high tuning degree of freedom, where channels can be actively reconfigured and their on/off states can be freely switched. Our study provides a strategy for the active regulation of topological states and may be beneficial for the development of reconfigurable topological optical devices.
作者机构：
[Liu, Dongbo; Zhang, Zhixu] State Key Lab Subhlth Intervent Technol, Changsha 410128, Hunan, Peoples R China.;[Liu, Dongbo; Zhang, Zhixu] Hunan Agr Univ, Coll Hort, Changsha 410128, Hunan, Peoples R China.;[Qin, Dan] Hunan Agr Univ, Coll Food Sci & Technol, Changsha 410128, Hunan, Peoples R China.;[Guo, Xin] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Hunan, Peoples R China.;[Lin, Haiyan] Natl Res Ctr Engn Technol Utilizat Ingredients Bot, Changsha 410128, Hunan, Peoples R China.
通讯机构：
[Guo, X ] C;Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Hunan, Peoples R China.
关键词：
Adsorption;Carbon dots;Pb(II);Starch
摘要：
The adsorption removal of lead (Pb) ions has become a crucial area of research due to the potential health hazards associated with Pb contamination. Developing cost-effective adsorbents for the removal of Pb(II) ions is significantly important. Hence, a novel fluorescent starch-based hydrogel (FSH) using starch (ST), cellulose nanofibrils (CN), and carbon dots (CD) was fabricated for simultaneous adsorption and detection of Pb(II). A comprehensive characterization of FSH, including its morphological features, chemical composition, and fluorescence characteristics, was conducted. Notably, FSH exhibited a maximum theoretical adsorption capacity of 265.9mg/g, which was 13.0 times higher than that of pure ST. Moreover, FSH was employed as a fluorescent sensor for Pb(II) determination, achieving a limit of detection (LOD) of 0.06μg/L. An analysis was further performed to investigate the adsorption and detection mechanisms of Pb(II) utilizing FSH. This study provides valuable insights into the production of a novel cost-effective ST-based adsorbent for the removal of Pb(II) ions.
通讯机构：
[Deng, T ] C;[Li, JS ] H;Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.;Cent South Univ Forestry & Technol, Sch Sci, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
摘要：
A novel AIEgen molecular probe (N-3QL) with typical AIE effects, good biocompatibility, lysosome targeting, pH activation, excellent photostability, and high brightness was synthesized using two simple synthetic steps. Spectroscopic and cytotoxicity experiments indicate that N-3QL can not only be used for the dynamic monitoring of cancer cell lysosomes, but also for photodynamic therapy (PDT) ablation of cancer cells. A pH-activated AIE molecular probe (N-3QL) was synthesized for the purpose of lysosome fluorescence tracking and PDT ablation of cancer cells.
作者机构：
[Ning Zhang] College of Science, Central South University of Forestry and Technology, Changsha 410004, P. R. China;[Dandan Gao; Ziyu Zhuang] Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, P. R. China;Key Lab of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Chinese Academy of Sciences, Xining 810008, P. R. China;College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China;[Dongdong Li] Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, P. R. China<&wdkj&>Key Lab of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Chinese Academy of Sciences, Xining 810008, P. R. China
通讯机构：
[Dongdong Li] Q;Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, P. R. China<&wdkj&>Key Lab of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Chinese Academy of Sciences, Xining 810008, P. R. China
摘要：
Lithium aluminum layered double hydroxide chlorides (LADH-Cl) have been widely used for lithium extraction from brine. Elevation of the performances of LADH-Cl sorbents urgently requires knowledge of the composition-structure-property relationship of LADH-Cl in lithium extraction applications, but these are still unclear. Herein, combining the phase equilibrium experiments, advanced solid characterization methods, and theoretical calculations, we constructed a cyclic work diagram of LADH-Cl for lithium capture from aqueous solution, where the reversible (de)hydration and (de)intercalation induced phase evolution of LADH-Cl dominates the apparent lithium "adsorption-desorption" behavior. It is found that the real active ingredient in LADH-Cl type lithium sorbents is a dihydrated LADH-Cl with an Al:Li molar ratio varying from 2 to 3. This reversible process indicates an ultimate reversible lithium (de)intercalation capacity of ∼10 mg of Li per g of LADH-Cl. Excessive lithium deintercalation results in the phase structure collapse of dihydrated LADH-Cl to form gibbsite. When interacting with a concentrated LiCl aqueous solution, gibbsite is easily converted into lithium saturated intercalated LADH-Cl phases. By further hydration with a diluted LiCl aqueous solution, this phase again converts to the active dihydrated LADH-Cl. In the whole cyclic progress, lithium ions thermodynamically favor staying in the Al-OH octahedral cavities, but the (de)intercalation of lithium has kinetic factors deriving from the variation of the Al-OH hydroxyl orientation. The present results provide fundamental knowledge for the rational design and application of LADH-Cl type lithium sorbents.
摘要：
Sb-based materials exhibit considerable potential for sodium-ion storage owing to their high theoretical capacities. However, the bulk properties of Sb-based materials always result in poor cycling and rate performances. To overcome these issues, pyridine-regulated Sb@InSbS3 ultrafine nanoplates loaded on reduced graphene oxides (Sb@InSbS3@rGO) were designed and synthesized. During the synthesis process, pyridine was initially adopted to coordinate with In3+, and uniformly dispersed In2S3 ultrafine nanoplates on reduced graphene oxide were generated after sulfidation. Next, partial In3+ was exchanged with Sb3+, and Sb@InSbS3@rGO was obtained by using the subsequent annealing method. The unique structure of Sb@InSbS3@rGO effectively shortened the transfer path of sodium ions and electrons and provided a high pseudocapacitance. As the anode in sodium-ion batteries, the Sb@InSbS3@rGO electrode demonstrated a significantly higher reversible capacity, better stability (445 mAh<middle dot>g(-1) at 0.1 A<middle dot>g(-1) after 200 cycles and 212 mAh<middle dot>g(-1) at 2 A<middle dot>g(-1) after 1200 cycles), and superior rate (210 mAh<middle dot>g(-1) at 6.4 A<middle dot>g(-1)) than the electrode without pyridine (355 mAh<middle dot>g(-1) at 0.1 A<middle dot>g(-1) after 55 cycles and 109 mAh<middle dot>g(-1) at 2 A<middle dot>g(-1) after 770 cycles). Furthermore, full cells were assembled by using the Sb@InSbS3@rGO as anode and Na3V2(PO4)(3) as cathode, which demonstrated good cycling and rate performances and exhibited promising application prospects. These results indicate that adjusting the microstructure of electrode materials through coordination balance is A<middle dot>good strategy for obtaining high-capacity, high-rate, and long-cycle sodium storage performances.
通讯机构：
[Qiu, RH ; Xiong, BQ ; Chen, Y ] H;Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.;Hunan Univ Chinese Med, Sch Med, Dept Physiol, Changsha 410208, Peoples R China.;Hunan Inst Sci & Technol, Dept Chem & Chem Engn, Yueyang 414006, Peoples R China.
摘要：
In this study, we present a nickel-catalyzed reductive C(sp3)–Sb coupling of unactivated alkyl chlorides with chlorostibines. This approach is highly versatile, tolerating various functional groups such as acetal, alkene, nitrile, amine, ester, silyl ether, thioether, and various heterocyclic compounds. Notably, the late-stage modification of bioactive molecules and the satisfactory anticancer activity against cancerous MDA-MB-231 also demonstrate the potential application.
关键词：
the three-terminal ballistic junction;the alpha-T-3 lattie;the anisotropic transport
摘要：
The three-terminal ballistic junction (TBJ) has promising applications in nanoelectronics. We investigate the transport properties of aα-T(3)-based TBJ, where two typical configurations are considered, i.e. the A- and Z-TBJ. It is found that both A- and Z-TBJ exhibit transmission anisotropy, and the transmission of the A-TBJ has stronger anisotropy than that of the Z-TBJ. The amplitude of the rectification coefficient is smaller than that of phosphorene TBJ, but larger than that of graphene TBJ. When the symmetrical input is applied, the output voltage curve exhibits symmetric behavior. While in the case of asymmetric input, the symmetric behavior is broken, and the maximum value of the output voltage can reach a positive value. Interestingly, the voltage output shows a dramatic nonlinear response which may be useful for the voltage diode application with a push-pull input voltage. In addition, the heat fluxes of the asymmetric input are much smaller than those of the symmetric input. The maximum value of the heat flux under the symmetric input exceeds twice of that under the asymmetric input. Our results are useful to design nanoelectronic devices based onα-T(3)TBJ.
期刊：
Separation and Purification Technology,2024年341:126909 ISSN：1383-5866
通讯作者：
Chao Huang<&wdkj&>Ping Wang
作者机构：
[Haoran Tian; Qingyu Wu; Qiuju Wu; Chengyou Sun; Jie Wei; Haiyin Xu; Chao Huang; Ping Wang] College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China;[Ruimei Zhang] College of Science, Central South University of Forestry and Technology, Changsha 410004, China;[Zhiming Liu] Department of Biology, Eastern New Mexico University, Portales, NM 88130, USA
通讯机构：
[Chao Huang; Ping Wang] C;College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China
摘要：
Nano zero-valent iron (nZVI) has been widely employed for the elimination of heavy metals from wastewater. However, the practical application of nZVI is greatly limited due to its fast aggregation and surface passivation. In this study, a carbon nanotube-supported nZVI composite (nZVI@CNTs) was synthesized and coupled with Shewanella oneidensis MR-1 to enhance the removal of Cr(VI) from aqueous media. The results demonstrated that the coupling of nZVI@CNTs and MR-1 (nZVI@CNTs/MR-1) exhibited superior performance in eliminating Cr(VI) compared to using nZVI@CNTs or MR-1 alone. Electrochemical characterization demonstrated that CNTs acting as electron shuttles improve the electron transfer from MR-1 to nZVI, thus facilitating the passivation layer dissolution. XRD analysis proved that MR-1 can effectively promote the dissolution of the Fe(III) passivation layer with the existence of CNTs. FTIR and XPS analyses confirmed that CNTs contain many functional groups (such as C − C and C = O) related to extracellular electron transfer, thus promoting the electron transfer of MR-1 to nZVI. Three-dimensional excitation-emission matrix (3D-EEM) analysis showed that the extracellular polymeric substances (EPS) generated from MR-1 participated in the Cr(VI) elimination. The mechanism analysis demonstrated the Fe(II) dissolved from the nZVI passivation layer reduces Cr(VI) to Cr(III) and then removes it by co-precipitation, and the EPS secreted by MR-1 also participates in the Cr(VI) adsorption and reduction. Generally, the coupling of nZVI@CNTs and MR-1 successfully addresses the drawbacks of nZVI and demonstrates a remarkable ability to remove Cr(VI).
作者机构：
[Liu, Zili; Hu, Xinjiang; Tian, Haoran; Xu, Haiyin; Sun, Chengyou; Zhu, Jian] College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China;[Huang, Chao] College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China. Electronic address: huangchao@csuft.edu.cn;[Wang, Ping] College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China. Electronic address: pingwang@csuft.edu.cn;[Yin, Jinglin] College of Science, Central South University of Forestry and Technology, Changsha 410004, China;[Liu, Zhiming] Department of Biology, Eastern New Mexico University, Portales, NM 88130, USA. Electronic address: zhiming.liu@enmu.edu
通讯机构：
[Liu, Zhiming] D;[Huang, Chao; Wang, Ping] C;College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China. Electronic address:;Department of Biology, Eastern New Mexico University, Portales, NM 88130, USA. Electronic address: zhiming.
摘要：
Fly ash (FA) and eggshells (ES) are common solid wastes with significant potential for the recovery of phosphorus from water. This study focuses on synthesizing a low-cost and environmental-friendly phosphate adsorbent called eggshell-fly ash geopolymer composite (EFG) using eggshells instead of chemicals. The CaO obtained from the high-temperature pyrolysis of eggshells provides active sites for phosphate adsorption, and CO(2) serves as a pore-forming agent. The phosphate adsorption performance of EFG varied with the eggshell-fly ash ratios and achieved a maximum of 49.92 mg P/g at an eggshell-fly ash ratio of 40 %. The adsorption process was well described by the pseudo-second-order model and the Langmuir model. EFG also exhibited a good regeneration performance through six-cycle experiments and achieved the highest phosphate desorption at pH 4.0. The results of the column experiment showed that EFG can be used as a filter media for phosphorus removal in a real-scale application with low cost. Soil burial test indicated saturated EFG has a good phosphate slow-release performance (maintained for up to 60 days). Overall, EFG has demonstrated to be a promising adsorbent for phosphorus recovery.
摘要：
The ultrasensitive detection of hepatitis C virus (HCV) nucleic acid is crucial for the early diagnosis of hepatitis C. In this study, by combining Ag@Au core/shell nanoparticle (Ag@AuNP)-based surface-enhanced Raman scattering (SERS) tag with hybridization chain reaction (HCR), a novel SERS-sensing method was developed for the ultrasensitive detection of HCV nucleic acid. This SERS-sensing system comprised two different SERS tags, which were constructed by modifying Ag@AuNP with a Raman reporter molecule of 4-ethynylbezaldehyde, two different hairpin-structured HCR sequences (H1 or H2), and a detection plate prepared by immobilizinga capture DNA sequence onto the Ag@AuNP layer surface of the detection wells. When thetarget nucleic acid was present, the two SERS tags were captured on the surface of the Ag@AuNP-coated detection well to generate many "hot spots" through HCR, forming a strong SERS signal and realizing the ultrasensitive detection of thetarget HCV nucleic acid. The limit of detection of the SERS-sensing method for HCV nucleic acid was 0.47 fM, and the linear range was from 1 to 10(5) fM.
作者：
Jie Ouyang;Liangliang Zhou;Yi Tian;Wanning Xiong;Lixin Wang;...
期刊：
Journal of Cleaner Production,2024年446:141503 ISSN：0959-6526
通讯作者：
Yongfeng Luo
作者机构：
[Jie Ouyang; Liangliang Zhou; Yi Tian; Wanning Xiong; Lixin Wang; Xi Ren; Qingquan Sheng; Zejun Li; Xiubo Liu; Yongfeng Luo] Hunan Province Key Laboratory of Materials Surface & Interface Science and Technology, College of Science, Material Science and Engineering School, Central South University of Forestry and Technology, Changsha, Hunan, 410004, PR China
通讯机构：
[Yongfeng Luo] H;Hunan Province Key Laboratory of Materials Surface & Interface Science and Technology, College of Science, Material Science and Engineering School, Central South University of Forestry and Technology, Changsha, Hunan, 410004, PR China
摘要：
The utilization of wood-derived carbon thick electrodes has demonstrated remarkable structural advantages in the realm of electrochemical energy storage and catalysis. Its exceptional structural stability, mechanical strength, and well-organized pore structure position it as a promising material for self-supporting electrodes. The multi-scale cross-linking of lignin, cellulose, and hemicellulose within the wood tracheid wall establishes a convenient prerequisite for structural modification. However, the significance of dynamic nanopores on wood tracheid walls in enhancing the microporous/mesoporous structure of wood-derived carbon electrodes has been overlooked due to the focus on operability of microscale array pores and wood decomposition processes. Here, we employ a straightforward, highly efficient, and environmentally sustainable solvent infiltration strategy to enhance the nanopore content within the wood tracheid wall, ultimately resulting in a significant enhancement of the microporous/mesoporous composition within the wood-derived electrode. The charge storage capacity of wood-derived carbon electrode is doubled through the implementation of a solvent permeation modification strategy, while its abundant micro/mesoporous structure also endows it with significant potential in the field of electrocatalysis. Therefore, this thermal and solvent permeation modification strategy is anticipated to supplant the conventional acid-base etching method and offer a novel research concept for the advancement of wood-based carbon electrodes with abundant pore structure and exceptional electrochemical properties.
作者机构：
[Chen, Sha; Du, Ci; Chen, Yao; Tang, Ying] Hunan Univ Technol, Coll Life Sci & Chem, Hunan Key Lab Biomed Mat & Devices, Zhuzhou 412007, Peoples R China.;[Wang, Tong; Zhang, Xin-Yi; Chen, Yao; Wang, Xiao-Zhi; Tang, Ying] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.;[Zhao, Han-Qing] Cent South Univ Forestry & Technol, Sch Sci, Inst Appl Chem, Changsha, Peoples R China.;[Chen, Sha] Zhuzhou City Joint Lab Environm Microbiol & Plant, Zhuzhou, Peoples R China.
通讯机构：
[Wang, T ; Chen, Y ; Chen, Y] H;Hunan Univ Technol, Coll Life Sci & Chem, Hunan Key Lab Biomed Mat & Devices, Zhuzhou 412007, Peoples R China.;Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.
关键词：
Atractylodes macrocephala Koidz.;ensemble learning;gas chromatography - mass spectrometry (GC-MS);high-performance liquid chromatography - mass spectrometry (LC-MS);inductively coupled plasma - mass spectrometry (ICP-MS)
摘要：
The use of data fusion based with multiple analytical techniques was investigated to provide the accurate geographical origin identification of Atractylodes macrocephala Koidz. (AMK). Inductively coupled plasma - mass spectrometry (ICP-MS), gas chromatography - mass spectrometry (GC-MS) and liquid chromatography - mass spectrometry (LC-MS) were used to characterize Hubei, Zhejiang, and Hunan production regions. After the implementation of data fusion, the ensemble learning method multi-forest joint network (MFJN) and classic machine learning methods were used to identify the AMK production regions. The MFJN based upon high-level data fusion distinguished AMK samples from different regions with the highest accuracy. The classification accurate rate of AMK in the prediction set was 95%, which was significantly better than the results obtained using twenty-five mineral element or nine bioactive component data sets. The results showed that mass spectrometry data fusion in combination with MFJN is suitable for the geographic origin determination of AMK and has potential to ensure this product's fair trade.
摘要：
This work innovatively used cellulose nanofibers as a photocatalyst carrier, which could recycle nano-photocatalysts and minimize nanoparticle aggregation. The morphology, structures, chemical composition, optical-electronic properties and photocatalytic performance of amino-modified carbon quantum dots-ZnO/cellulose nanofiber (N-CQDs-ZnO/CNF: ZCH-2) hydrogel were characterized by SEM, TEM, BET, EDS, XRD, FTIR, UV-vis, XPS, PL and other techniques. The mechanism of Cr(VI) adsorption synergistic photoreduction by ZCH-2 was discussed in detail. The results showed that the prepared ZCH-2 had excellent removal performance for Cr(VI). After 120min of adsorption and 40min of photoreduction, the removal efficiency of Cr(VI) was 98.9%. Compared with ZnO/CNF hydrogel, the adsorption performance of ZCH-2 increased by 268% and the photoreduction performance increased by 116%. The adsorption of Cr(VI) by ZCH-2 was controlled by electrostatic attraction and chemical adsorption. The photoreduction kinetic constant of ZCH-2 was 0.106min(-1), which was 8.9 times that of ZnO/CNF hydrogel. The N-CQDs in ZCH-2 could form N-CQDs-metal complexes with Cr(VI), resulting in fluorescence quenching, so Cr(VI) could be visually identified by fluorescence changes. This study provides a new idea for the design and optimization of a new multifunctional hydrogel with efficient adsorption-photoreduction-fluorescence recognition.
作者机构：
[Peng, Chuan-Chong; Wu, LJ; Wu, Li-Jun; Long, Fang; Zhang, Kai-Yi; Liu, Jin-Hui] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.;[Long, Fang] ChangSha Commerce & Tourism Coll, Dept Hunan Cuisine, Changsha 410116, Peoples R China.;[Feng, Rui] Capital Normal Univ, Dept Chem, Beijing 100089, Peoples R China.
通讯机构：
[Wu, LJ ] C;Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.
摘要：
A novel alkyl radical-initiated alkylsulfonylation of alkenes via copper carbene coupling is developed for the synthesis of various alkyl-alkyl sulfones by employing potassium metabisulphite (K2S2O5) as a connector. In this reaction, readily available K2S2O5 not only serves as a sulfur dioxide source but is also demonstrated to be an efficient reducing agent for promoting the catalytic cycle. Notably, the late-stage modifications of bioactive molecules including estrone and cholesterol derivatives utilizing this protocol could also be achieved. Mechanistic investigations reveal that the transformation involves intramolecular radical cyclization, insertion of "SO2" and the coupling of copper carbenes in a single reaction step. A novel alkyl radical-initiated alkylsulfonylation of alkenes involving copper carbene coupling is developed for the synthesis of various alkyl-alkyl sulfones by employing potassium metabisulphite (K2S2O5) as a connector.
摘要：
A novel cellulose nanofibril/titanate nanofiber modified with CdS quantum dots hydrogel (CTH) was synthesized as an effective, stable, and recyclable photocatalytic adsorbent using cellulose nanofibril (CN), titanate nanofiber (TN), and CdS quantum dots. Within the CTH structure, CN formed an essential framework, creating a three-dimensional (3D) porous structure that enhanced the specific surface area and provided abundant adsorption sites for Cr(VI). Simultaneously, TN modified with CdS quantum dots (TN-CdS) served as a nanoscale Z-type photocatalyst, facilitating the efficient separation of photoinduced electrons and holes, further increasing the photocatalytic efficiency. The morphological, chemical, and optical properties of CTH were thoroughly characterized. The CTH demonstrated the maximum theoretical adsorption capacity of 373.3±14.2mg/g, which was 3.4 times higher than that of CN hydrogel. Furthermore, the photocatalytic reduction rate constant of the CTH was 0.0586±0.0038min(-1), which was 6.4 times higher than that of TN-CdS. Notably, CTH displayed outstanding stability, maintaining 84.9% of its initial removal efficiency even after undergoing five consecutive adsorption-desorption cycles. The remarkable performance of CTH in Cr(VI) removal was attributed to its 3D porous structure, comprising CN and TN-CdS. These findings provide novel insights into developing a stable photocatalytic adsorbent for Cr(VI) removal.
期刊：
Industrial Crops and Products,2024年210:118162 ISSN：0926-6690
通讯作者：
Xin Guo<&wdkj&>Yiqiang Wu
作者机构：
[Xinmiao Qi; Meng Liu; Xuefeng Zhang; Qiang Ma; Xin Guo] College of Science, Central South University of Forestry and Technology, Changsha 410004, China;[Yizheng Chen] Hunan Provincial Key Laboratory of Environmental Catalysis and Waste Recycling, School of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, China;[Yingfeng Zuo; Yiqiang Wu] College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China;[Xiangjing Xie] College of Textiles and Clothing, Hunan Institute of Engineering, Xiangtan 411104, China
通讯机构：
[Xin Guo; Yiqiang Wu] C;College of Science, Central South University of Forestry and Technology, Changsha 410004, China<&wdkj&>College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China
摘要：
For the high-value utilization of wood, a novel non-cytotoxic bifunctional wood (NBW) was synthesized in this study for simultaneous adsorption and detection of Pb(II). Adsorption experiments showcased the remarkable maximum adsorption capacity of NBW, measuring 211.6 mg/g. The adsorption isotherm followed the Langmuir model, and concurrently, adsorption kinetics adhered to the pseudo-second-order model. Critically, NBW exhibited exceptional reusability, maintaining 81.0% of its initial adsorption capacity even after undergoing six consecutive adsorption/desorption cycles. Additionally, it demonstrated notable temporal stability, preserving more than 84.2% of its initial adsorption capacity after a fifteen-week storage period. Furthermore, NBW was used for selective and sensitive detection of Pb(II), yielding a low limit of detection of 0.13 μg/L. The fluorescence quenching of NBW resulted from both the internal filtering effect and dynamic quenching. Importantly, the cost analysis demonstrated that the expense of removing Pb(II) per gram using NBW was only CNY 0.50, significantly lower than the cost associated with activated carbon, totaling CNY 2.11. This study lays the groundwork for the development of a long-term stable, reusable, cost-effective, and multifunctional adsorbent.
期刊：
Process Safety and Environmental Protection,2024年182:405-415 ISSN：0957-5820
通讯作者：
Xu, T
作者机构：
[Tang, Xiting; Zeng, Zhen] Cent South Univ Forestry & Technol, Sch Life Sci & technol, Changsha 410004, Peoples R China.;[Xu, T; Zhou, Yihui; Xu, Tao] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.;[Wu, Qingyu; Liu, Kang; Hu, Simeng] Cent South Univ Forestry & Technol, Coll Environm Sci & Engn, Changsha 410004, Peoples R China.;[Xu, Tao; Yu, Gang] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China.;[Zhou, Yihui; He, Miao] Aerosp Kaitian Environm Technol Co Ltd, Changsha 410100, Peoples R China.
通讯机构：
[Xu, T ] C;Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.
关键词：
Sinusoidal alternating current coagulation;Heavy metal ions;Process evaluation;Adsorption behavior;Removal mechanism
摘要：
A novel photovoltaic energy-sinusoidal alternating current coagulation (PE-SACC) system was proposed for the removal of heavy metal ions (HMs) in electroplating wastewater. A response surface methodology was used to study the combined effect of two factors on removal efficiency (Re) and energy consumption (EEC), and the optimal process parameters were obtained. The morphology, surface element content, crystal structure, and chemical composition of the flocs generated during the electrocoagulation (EC) process were characterized using SEM, EDS, XRD, FTIR, and XPS techniques. The intra-particle diffusion model was used to describe the adsorption behavior of HMs (Cu2+, Zn2+ and Ni2+) by flocs. Finally, the removal mechanism of HMs by SACC technology and its application in actual wastewater treatment were discussed in detail. The results revealed that when c(0)(Ni2+) = c(0)(Zn2+) = c(0)(Cu2+) = 50 mg.dm(-3), c (Cl ) over bar = 100 mg.dm(-3), pH(0) = 10, j = 1.3 A.m(-2), t = 85 min, the Re(Cu2+), Re(Zn2+) and Re(Ni2+) were 99.3%, 99.1%, and 98.4%, respectively, and the EEC was 0.105 kWh.m(-3). Compared with the traditional direct current coagulation (DCC), EEC, electrode consumption, and sludge production in SACC mode were reduced by 37.1%, 62.2%, and 66.6%, respectively. The PE-SACC system achieved ultra-low cost treatment of heavy metal electroplating wastewater. The adsorption process included surface adsorption, pore adsorption, and adsorption equilibrium. The mechanisms for the removal of HMs included cathode reduction, alkaline precipitation, and adsorption. In the actual wastewater treatment process, the removal efficiency of HMs could still be maintained above 99%, and the effluent met the national discharge standard (GB 31574-2015). This study presented an economically and environmentally sustainable approach for the evolution and industrial utilization of novel electrocoagulation technologies.
关键词：
S -type heterostructure;Tetracycline hydrochloride;Photocatalysis;tc-COF
摘要：
Photocatalytic oxidation is a promising technology for wastewater treatment. It is a more desirable method than other conventional wastewater treatment approaches due to its low cost, environmental friendly, and capability to completely degrade pollutants into environmentally safe products under appropriate conditions. Among some photocatalysts, covalent organic frameworks with high photoactivity are recognized as stable and feasible materials for this purpose. In this work, highly-effective photocatalyst of S-type heterostructure tc-COF was successfully synthesized by using ultrasonic delamination treatment sp2c-COF nanosheets (sp2c-NS) and py-NH2COF nanosheets (Py-NH2-NS) via a secondary solvent heating method. The preparation was initiated by synthesizing sp2c-COF and py-NH2-COF successfully adopting pyrene templates by solvothermal method. The study focused on physicochemical characterization and photocatalytic activity of tc-COF. The photocatalytic ability of tc-COF was carried out to degrade tetracycline under visible light. The results indicate that tc-COF not only shows excellent photocatalytic activity for tetracycline degradation of 94.8 % at 90 min under visible light illumination, but also has good photocatalytic degradation performance at wide initial pH values, coexisting ions, and actual water sources. Surprisingly, it has excellent stability and recyclability, it can afford high oxidative degradation (87.3 %) even after 5 successive recycles. The degradation mechanism was discussed by various methods such as active species trapping experiment, electron paramagnetic resonance determination and related electrochemical analysis. In addition, the main degradation intermediate products and the possible pathways of TC degradation were detected and proposed according to LC - MS technology. This work provided a new strategy for the preparation of hetero-structured COF which could be served as an advantageous photocatalyst for the treatment of pharmaceutical industry wastewater.
