Phase Chemistry for Hydration Sensitive (De)intercalation of Lithium Aluminum Layered Double Hydroxide Chlorides

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成果类型：

期刊论文

作者：

Dongdong Li*;Ning Zhang;Dandan Gao;Ziyu Zhuang;Dewen Zeng

通讯作者：

Dongdong Li

作者机构：

[Ning Zhang] College of Science, Central South University of Forestry and Technology, Changsha 410004, P. R. China

[Dandan Gao; Ziyu Zhuang] Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, P. R. China

Key Lab of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Chinese Academy of Sciences, Xining 810008, P. R. China

College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China

[Dongdong Li] Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, P. R. China<&wdkj&>Key Lab of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Chinese Academy of Sciences, Xining 810008, P. R. China

通讯机构：

[Dongdong Li] Q

Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, P. R. China<&wdkj&>Key Lab of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Chinese Academy of Sciences, Xining 810008, P. R. China

语种：

英文

关键词：

lithium;sorbent;LADH-Cl;phase evolution;hydration;intercalation;deintercalation

期刊：

ACS Materials Au

ISSN：

2694-2461

年：

2024

卷：

期：

页码：

45-54

DOI：

10.1021/acsmaterialsau.3c00063

基金类别：

Natural Science Foundation of Hunan Province#&#&#2023JJ31014 National Key Research and Development Program of China#&#&#2022YFC2906200#&#&#2022YFC3900905 West Light Foundation, Chinese Academy of Sciences#&#&#292022000019 National Natural Science Foundation of China#&#&#52234001

机构署名：

本校为第一机构

院系归属：

理学院

摘要：

Lithium aluminum layered double hydroxide chlorides (LADH-Cl) have been widely used for lithium extraction from brine. Elevation of the performances of LADH-Cl sorbents urgently requires knowledge of the composition-structure-property relationship of LADH-Cl in lithium extraction applications, but these are still unclear. Herein, combining the phase equilibrium experiments, advanced solid characterization methods, and theoretical calculations, we constructed a cyclic work diagram of LADH-Cl for lithium capture from aqueous solution, where the r...

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Phase Chemistry for Hydration Sensitive (De)intercalation of Lithium Aluminum Layered Double Hydroxide Chlorides

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