二乙酸乙酯基系列分散染料合成及染色研究
作者：
胡仁杰;熊远福;赵莹;谭晓燕;袁遥
期刊：
湖南师范大学自然科学学报 ,2020年43(2):69-76 ISSN：2096-5281
作者机构：
湖南农业大学理学院,中国 长沙 410026;中南林业科技大学理学院,中国 长沙 10004;[胡仁杰; 熊远福] 湖南农业大学;[赵莹; 袁遥; 谭晓燕] 中南林业科技大学
关键词：
氯乙酸乙酯;还原物;分散染料;改性木粉;染色
摘要：
以3-(N,N-二乙酸乙酯基)氨基-4-甲氧基乙酰苯胺为偶合组份,2-氨基-3,5-二硝基噻吩、3-氨基-5-硝基-2,1-苯并异噻唑、4-硝基苯胺、2,4-二硝基-6-氯苯胺和2,4-二硝基-6-溴苯胺为重氮组分,经重氮化-偶合反应合成了5个二乙酸乙酯基系列偶氮分散染料;用UV-Vis,IR,1 HNMR和MS对其进行结构表征,并探索其对涤纶织物和改性木粉的染色性能.结果表明:所合成的5个二乙酸乙酯基系列偶氮分散染料为目标产物,其最大可见吸收波长为513～655 nm(丙酮);染色涤纶织物的色光分别为蓝绿色、艳绿色、红色、蓝紫色和蓝紫色,并体现高皂洗牢度和高日晒牢度特征;染色乙酰化木粉和染色苄基化木粉的色光与染色涤纶织物的色光类似,但稍暗.
语种：
中文
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氯乙烷的生产技术状况及其发展趋势
作者：
袁遥;赵莹;胡仁杰;熊远福;谭晓燕
期刊：
现代化工 ,2019年39(8):64-68 ISSN：0253-4320
通讯作者：
Zhao, Y.
作者机构：
中南林业科技大学理学院, 湖南, 长沙, 410004;湖南农业大学理学院, 湖南, 长沙, 410026;[袁遥; 赵莹; 谭晓燕] 中南林业科技大学理学院, 湖南, 长沙, 410004;[胡仁杰; 熊远福] 湖南农业大学理学院, 湖南, 长沙, 410026
通讯机构：
College of Science, Central South University of Forestry and Technology, Changsha, China
关键词：
氯乙烷;氯化氢;氯化锌;乙基化反应;三氯乙醛;亚磷酸二乙酯
摘要：
介绍了氯乙烷生产技术主要涉及的氯化氢来源、催化体系、合成工艺、分离与精制、生产设备和自动控制技术等6个方面。采用乙醇-氯化氢法实现清洁化生产、合成反应釜大型化提高产能、多级精馏设备与固体吸附剂相结合提高氯乙烷品质、应用自动控制技术提高生产效率等是我国氯乙烷的生产技术现状。利用副产物氯化氢气体、应用智能制造技术控制生产过程和研发乙烯-氯化氢法是我国生产氯乙烷技术的发展方向。
语种：
中文
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我国氯乙烷市场需求与生产状况
作者：
谭晓燕;赵莹;胡仁杰;熊远福;袁遥
期刊：
现代化工 ,2019年39(3):9-15 ISSN：0253-4320
通讯作者：
Zhao, Y.
作者机构：
中南林业科技大学理学院,湖南长沙,410004;湖南农业大学理学院,湖南长沙,410026
通讯机构：
College of Science, Central South University of Forestry and Technology, Changsha, China
关键词：
氯乙烷;乙基化;四乙基铅;染料中间体;香料
摘要：
总结了我国氯乙烷的需求现状、生产企业及产能,分析了我国氯乙烷供需状况和氯乙烷生产企业间的竞争状况。我国氯乙烷需求量约5. 6万t/a,其中在染料中间体合成上的需求量占总需求量的48%,居第一位;氯乙烷总产能达11万t/a,其中合成氯乙烷产能10万t/a,合成氯乙烷企业不宜再扩大生产规模。
语种：
中文
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多微孔苄基化木粉对Cu~(2+)和Pb~(2+)的吸附研究
作者：
杨瑶;周夏禹;赵莹;谭晓燕;田潇潇;...
期刊：
环境科学学报 ,2016年36(3):857-864 ISSN：0253-2468
通讯作者：
Zhao, Y.
作者机构：
[杨瑶; 赵莹; 谭晓燕; 田潇潇; 邓婷] College of Science, Central South University of Forestry & Technology, Changsha, 410004, China;[周夏禹] Changde Vocational Technical College, Changde, 415000, China
通讯机构：
College of Science, Central South University of Forestry & Technology, Changsha, China
关键词：
木粉;苄基化反应;吸附
摘要：
以中国杉木粉为研究对象,经苄基化改性和水热处理制得多微孔苄基化木粉.同时,以多微孔苄基化木粉为吸附材料,研究了苄基化木粉的增重率、溶液的pH值、接触时间、离子初始浓度和吸附温度等因素对Cu~(2+)和Pb~(2+)吸附效果的影响,并采用红外光谱、扫描电镜、核磁共振等分析手段对木粉改性与水热处理前后的材料进行了结构表征.结果表明:木粉经苄基化改性及水热处理后所制得的多微孔苄基化木粉对Cu~(2+)和Pb~(2+)的吸附百分率比原木粉分别提高57%和209%,木粉的苄基化程度、溶液的pH值、接触时间、离子初始浓度和温度是影响Cu~(2+)和Pb~(2+)吸附百分率的重要因素.当溶液的pH值为5.5,Cu~(2+)和Pb~(2+)的浓度为30 mg·L~(-1),吸附温度为40 ℃,吸附时间为60 min,多微孔苄基化木粉质量为溶液质量的2.0%时,Cu~(2+)去除率达94.4%,Pb~(2+)去除率达88.7%.
语种：
中文
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多微孔苄基木粉的制备及其对铜离子的吸附性能
作者：
杨瑶;谭晓燕;赵莹;汤静芳;王赛;...
期刊：
湖南师范大学自然科学学报 ,2015年38(1):28-32,44 ISSN：2096-5281
作者机构：
中南林业科技大学理学院,中国长沙,410004;[王赛; 赵莹; 汤静芳; 戴瑜; 杨瑶; 谭晓燕] 中南林业科技大学
关键词：
木材改性;苄基木粉;铜离子;原子吸收光谱;吸附
摘要：
将杉木粉进行苄基化改性反应,再经高温水蒸汽爆破处理制得多微孔苄基木粉,用红外光谱、扫描电镜对杉木粉改性前后的结构进行了表征.以多微孔苄基木粉为吸附剂,用原子吸收光谱研究了体系初始p H值、铜离子浓度、吸附温度和吸附时间等因素对铜离子的吸附效率.结果表明,多微孔苄基木粉对铜离子的吸附能力高于原木粉、脱脂木粉和苄基木粉;当溶液的p H值为4.0、铜离子浓度为40 mg/L、吸附温度为40℃、吸附时间为45min,多微孔苄基木粉质量为溶液质量的0.8%时,铜离子的去除率高达99%.
语种：
中文
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DYEING OF ACETYLATED WOOD WITH DISPERSE DYES
作者：
Zhao, Ying* ;Tan, Xiaoyan;Wan, Xiaoqiao;Yuan, Yao;Yu, Zehua;...
期刊：
Wood and Fiber Science ,2014年46(3):401-411 ISSN：0735-6161
通讯作者：
Zhao, Ying
作者机构：
[Tang, Jingfang; Tan, Xiaoyan; Wan, Xiaoqiao; Yuan, Yao; Yu, Zehua; Zhao, Ying] Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
通讯机构：
[Zhao, Ying] C;Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
关键词：
Wood modification;acetylated wood;wood dyeing;disperse dyes;color shade
摘要：
In this study, fir powder and acetylated fir powder were dyed using a series of disperse dyes under high temperature and pressure and were compared with the dyeing of polyester under the same condition. Acetylated oak and poplar veneer were also dyed as a reference. Unmodified fir powder, acetylated fir powder, and dyed acetylated fir powder were characterized by IR spectra and scanning electron microscope. The effect of pH value and dye concentration on the dyeing properties and fastness was evaluated and compared. Disperse dyes exhibited better dyeability and fastness on acetylated fir powder than on unmodified fir powder. This was because of the differences in the structures of the two fir powders. ©2014 by the Society of Wood Science and Technology.
语种：
英文
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Preparation and Dyeing of Ethylated Wood Plastic Composites
作者：
Jingfang Tang;Ying Zhao;Xiaoyan Tan;Xiaoqiao Wan;Yu Dai
期刊：
Advanced Materials Research ,2013年742:192-196 ISSN：1022-6680
通讯作者：
Zhao, Y.
作者机构：
[Tang J.F.; Wan X.Q.; Zhao Y.; Tan X.Y.; Dai Y.] The Institute of Applied Chemistry, Central South University of Forestry and Technology, Changsha, 410004, China
通讯机构：
[Zhao, Y.] T;The Institute of Applied Chemistry, , Changsha, 410004, China
会议名称：
2013 International Conference on Civil,Materials and Environmental Sciences(CMES 2013)
会议时间：
2013-04-17
会议地点：
Vancouver,Canada
关键词：
Disperse dyes;Ethylated wood;Wood dyeing;Wood plastic composite
摘要：
In this study, ethylated wood powder/polystyrene plastic composite (WPC) was obtained by combining ethylated Chinese Fir powder with polystyrene foam in DMF or CHCl3, and was dyed with disperse dyes. The results show that the compatibility of ethylated fir powder with polystyrene was good when the ratio of wood to plastic ratio is beyond 3:1. The color shade of dyed wood-plastic powder is close to that of dyed polyester fabric and high temperature is favorable for the dyeing of wood-plastic powder. Moreover, dyed wood plastic powder has good washing fastness, which depends on the molecular structure of disperse dyes, dye concentration and dyeing temperature. © (2013) Trans Tech Publications, Switzerland.
语种：
英文
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Effect of Molar Ratio of Citric Acid to Metal Nitrate on the Structure and Catalytic Activity of NiO Nanoparticles
作者：
Wu Gang;Tan Xiao-yan;Li Gui-ying* ;Hu Chang-wei
期刊：
高等学校化学研究：英文版 ,2013年29(1):154-158 ISSN：1005-9040
通讯作者：
Li Gui-ying
作者机构：
[Li Gui-ying; Hu Chang-wei; Tan Xiao-yan; Wu Gang] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China.;[Wu Gang] Southwest Jiaotong Univ Emei, Dept Basic Courses, Emeishan 614202, Peoples R China.;[Tan Xiao-yan] Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 412006, Hunan, Peoples R China.
通讯机构：
[Li Gui-ying] S;Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China.
关键词：
Nanostructure;Sol-gel growth;X-Ray diffraction;Surface property
摘要：
NiO nanoparticles were prepared by means of sol-gel method via varying the ratio of citric acid to nickel nitrate. The samples were characterized by powder X-ray diffraction(XRD), Fourier transform infrared(FTIR) spectroscopy, transmission electron microscopy(TEM) and X-ray photoelectron spectroscopy(XPS). It was found that the molar ratio of citric acid to nickel nitrate has a great effect on the crystal structure and particle size of NiO. The increase of the molar ratio of citric acid to nickel nitrate is favorable to the formation of NiO smaller particles within the range tested. Compared to bulk NiO obtained by thermal decomposition, NiO nanoparticles possess more surface oxygen species O-. The activity test indicates that surface oxygen species O- plays a crucial role in the hydroxylation of benzene to phenol with hydrogen peroxide as oxidant. The active site may be originated from Ni2+ on the surface of the samples, while Ni0 does not contribute to the hydroxylation reaction. © 2013 Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH.
语种：
英文
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Adsorption of Pb(II) on activated carbon treated by nitric acid
作者：
Tan, Xiaoyan* ;Zhao, Fang;Wen, Ruizhi;Dai, Yu
期刊：
Advanced Materials Research ,2012年550-553:2190-2193 ISSN：1022-6680
通讯作者：
Tan, Xiaoyan
作者机构：
[Dai, Yu; Tan, Xiaoyan; Zhao, Fang; Wen, Ruizhi] Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
通讯机构：
[Tan, Xiaoyan] C;Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
会议名称：
2nd International Conference on Chemical Engineering and Advanced Materials (CEAM 2012)
会议时间：
JUL 13-15, 2012
会议地点：
Guangzhou, PEOPLES R CHINA
会议主办单位：
[Tan, Xiaoyan;Zhao, Fang;Wen, Ruizhi;Dai, Yu] Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
会议论文集名称：
Advanced Materials Research
关键词：
Activated carbon;Adsorption;Surface property;Wasterwater treatment
摘要：
Commercially available coal-based activated carbon was treated with different concentration of nitric acid. The resultant samples were used to adsorb lead from aqueous solution. N2 adsorption, Boehm titration, point of zero charge (pHPZC) and X-ray photoelectron spectroscopy (XPS) were used to characterize the samples. Acidic pH is favorable for Pb(Ⅱ) adsorption. The acidic groups increase significantly with the increment of the concentration of nitric acid during the treatment. The carboxylic groups of surface carbon play an important role in the adsorption process.
语种：
英文
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Adsorption of Phenol onto Activated Carbons
作者：
Tan, Xiaoyan* ;Li, Guolan;Li, Song
期刊：
Advanced Materials Research ,2012年531:407-410 ISSN：1022-6680
通讯作者：
Tan, Xiaoyan
作者机构：
[Tan, Xiaoyan] Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.;[Li, Song; Li, Guolan] Mianyang Normal Univ, Sch Chem & Chem Engn, Mianyang, Peoples R China.
通讯机构：
[Tan, Xiaoyan] C;Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
会议名称：
2nd International Conference on Material Engineering, Chemistry, Bioinformatics (MECB 2012)
会议时间：
JUL 14-15, 2012
会议地点：
Xian, PEOPLES R CHINA
会议主办单位：
[Tan, Xiaoyan] Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.^[Li, Guolan;Li, Song] Mianyang Normal Univ, Sch Chem & Chem Engn, Mianyang, Peoples R China.
会议论文集名称：
Advanced Materials Research
关键词：
Activated carbon;Adsorption;Kinetics;Wasterwater treatment
摘要：
Coal-based Activated carbon was modified by thermal and nitric acid treatment to adsorb phenol from aqueous solution. Boehm titration, point of zero charge (pHPZC) and X-photoelectron spectroscopy (XPS) were used to characterize activated carbons. Acid treatment leads to the increase of the content of surface oxygen, whereas thermal treatment causes the decrease of the content of surface oxygen. The surface characteristics of activated carbons have significant effect on phenol adsorption. The adsorption isotherms of phenol adsorption are described by Langmuir isotherm. The kinetic studies indicate that the adsorption process is fitted well by the pseudo-second- order kinetics. ©(2012) Trans Tech Publications, Switzerland.
语种：
英文
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Dyeing properties of acetylated wood with red disperse dyes
作者：
Zhao, Ying* ;Tan, Xiaoyan;Wan, Xiaoqiao;Liu, Wei;Yu, Zehua
期刊：
Advanced Materials Research ,2011年335-336(671):1061-1066 ISSN：1022-6680
通讯作者：
Zhao, Ying
作者机构：
[Liu, Wei; Tan, Xiaoyan; Wan, Xiaoqiao; Yu, Zehua; Zhao, Ying] Cent S Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
通讯机构：
[Zhao, Ying] C;Cent S Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
会议名称：
International Conference on Materials and Products Manufacturing Technology
会议时间：
OCT 28-30, 2011
会议地点：
Chengdu, PEOPLES R CHINA
会议主办单位：
[Zhao, Ying;Tan, Xiaoyan;Wan, Xiaoqiao;Liu, Wei;Yu, Zehua] Cent S Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
会议论文集名称：
Advanced Materials Research
关键词：
Acetylated wood;Color difference;Color fastness to washing;Percentage of dye exhaustion;Wood dyeing
摘要：
The dyeing properties of acetylated fir powder and acetylated poplar spill with 8 red disperse dyes were studied in this paper. The dyeing results indicate that the percentage of dye exhaustion (% E)on acetylated fir powder is 96~99%. As for acetylated poplar spill, the percentage of dye exhaustion reaches 58~78%. The color shade of dyed modified wood is similar to that of dyed polyester fabric. Compared with the dyed polyester fabric, the color difference(∆E) of dyed modified wood is smaller than that of dyed unmodified wood under the same dyeing conditions. Furthermore, modified fir powder has excellent color fastness to washing, the dye removal of dyed acetylated fir powder is 0.4 ~ 1.8 % at 80°C for 2 h in the water. Both the Infrared (IR) spectra and microscopic images of fir powder, acetylated fir powder and dyed acetylated fir powder were investigated.
语种：
英文
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Effect of calcination temperature on the structure and hydroxylation activity of Ni0.5Cu0.5Fe2O4 nanoparticles
作者：
Tan, Xiaoyan;Zhao, Ying;Li, Guiying* ;Hu, Changwei
期刊：
Applied Surface Science ,2011年257(14):6256-6263 ISSN：0169-4332
通讯作者：
Li, Guiying
作者机构：
[Hu, Changwei; Tan, Xiaoyan; Li, Guiying] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China.;[Tan, Xiaoyan; Zhao, Ying] Cent S Univ Forestry & Technol, Inst Appl Chem, Changsha 412006, Hunan, Peoples R China.
通讯机构：
[Li, Guiying] S;Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China.
关键词：
Nanocrystalline Ni0.5Cu0.5Fe2O4;Surface characteristics;Sol-gel method;XPS;Hydroxylation
摘要：
Nanocrystalline Ni0.5Cu0.5Fe2O4 was synthesized by sol–gel method with varying calcination temperature over the range of 500–1000. The powders obtained were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). In addition, thermal analysis (TG–DTG–DTA) of the precursor was carried out. The study reveals the simultaneous decomposition and ferritization process at rather low temperature (280–350). For the crystalline structure investigated, single cubic spinel is gained when the precursor was decomposed at 800–1000, whereas separated crystal CuO formed when calcination temperature is below 800. The increase of calcination temperature favors the appearance of FeB3+, CuA2+ and O on the spinel surface. The hydroxylation activity is relative to the amount of CuB2+ species on the spinel surface. The lattice oxygen species on the spinel surface are favorable for the deep oxidation of phenol.
语种：
英文
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Effect of preparation method on the surface properties and activity of Ni0.7Cu0.3Fe2O4 nanoparticles
作者：
Tan, Xiaoyan;Li, Guiying;Zhao, Ying;Hu, Changwei*
期刊：
Journal of Alloys and Compounds ,2010年493(1-2):55-63 ISSN：0925-8388
通讯作者：
Hu, Changwei
作者机构：
[Hu, Changwei; Tan, Xiaoyan; Li, Guiying] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China.;[Tan, Xiaoyan; Zhao, Ying] Cent S Univ Forestry & Technol, Inst Appl Chem, Changsha 412006, Hunan, Peoples R China.
通讯机构：
[Hu, Changwei] S;Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China.
关键词：
BET surface area measurement;Coprecipitation method;Crystallization temperature;Cubic spinel structure;Decomposition process;Differential thermals;Direct oxidation;Experimental studies;Fourier transform infrared;Inductively coupled plasma spectroscopy;Milling methods;Octahedral sites;Preparation method;SEM;Single phase;Sol-gel combustion;Spinel formation;TEM;Temperature-programmed reduction;Thermal analysis;XPS;XRD analysis;Benzene;Benzene refining;Catalysis;Combustion;Diffraction;Gels;Hydrogen peroxide;Inductively coupled plasma;Infrared spectroscopy;Milling (machining);Nanoparticles;Nanostructured materials;Oxidation;Phenols;Precipitation (chemical);Scanning electron microscopy;Sol-gel process;Sol-gels;Sols;Surface properties;Thermoanalysis;Transmission electron microscopy;X ray diffraction;X ray diffraction analysis;X ray photoelectron spectroscopy
摘要：
Ni0.7Cu0.3Fe2O4 nanoparticles were synthesized via sol-gel combustion technique, co-precipitation method and solid state milling method. Simultaneous thermogravimetric and differential thermal analysis (TG-DTA) was carried out to monitor the decomposition process of the precursors. The samples were characterized by Fourier transform infrared (FT-IR), inductively coupled plasma spectroscopy (ICPS), X-ray diffraction (XRD), BET surface area measurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM), temperature programmed reduction (TPR) and X-ray photoelectron spectroscopy (XPS). TG-DTA traces of the precursors show that the crystallization temperature for spinel formation by sol-gel combustion technique is lower than those by co-precipitation method and solid state milling method. XRD analysis reveals that the powders obtained are single phase with cubic spinel structure. Mutual promotion of reduction performance between CuO and NiFe2O4 is observed from TPR patterns. The experimental study indicates that the copper in the octahedral sites plays a crucial role in the direct oxidation of benzene with hydrogen peroxide as oxidant to phenol. © 2009 Elsevier B.V. All rights reserved.
语种：
英文
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4-乙基-N,N-二氰乙基苯胺催化合成研究
作者：
谭晓燕;赵莹;李姣娟;文瑞芝
期刊：
化工时刊 ,2010年24(7):19-21 ISSN：1002-154X
作者机构：
中南林业科技大学应用化学研究所,湖南,株洲,412006;[文瑞芝; 赵莹; 李姣娟; 谭晓燕] 中南林业科技大学
关键词：
丙烯腈;4-乙基苯胺;4-乙基-N;N-二氰乙基苯胺
摘要：
4-乙基苯胺与丙烯腈在AlCl3的催化下发生加成反应合成4-乙基-N,N-二氰乙基苯胺,其合适的反应条件是：AlCl3的用量为4-乙基苯胺质量的30%,反应温度为78～90℃,反应时间为8 h.结果表明：AlCl3对该反应具有很高的催化效率,目标产物收率可达93%.同时对4-乙基-N,N-二氰乙基苯胺的物性和结构进行了表征.
语种：
中文
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邻位和间位取代苯胺与丙烯腈的单氰乙基化反应
作者：
赵莹;赵芳;谭晓燕;李姣娟
期刊：
化学通报 ,2010年73(1):83-87 ISSN：0441-3776
通讯作者：
Zhao, Y.
作者机构：
[赵芳; 谭晓燕; 赵莹; 李姣娟] Institute of Applied Chemistry, Central South University of Forestry and Technology, Zhuzhou 412006, China
通讯机构：
[Zhao, Y.] I;Institute of Applied Chemistry, , Zhuzhou 412006, China
关键词：
氰乙基化反应;取代苯胺;气相色谱分析
摘要：
对于邻位、间位取代苯胺与丙烯腈发生单氰乙基反应生成相应的N-氰乙基邻位取代苯胺和N-氰乙基间位取代苯胺的过程, AlCl_3具有高的催化活性. 在芳香胺/丙烯腈/AlCl_3=1/1.10/(0.05~0.10)(摩尔比)、反应温度60~80℃,反应时间6 ~10 h的条件下,反应的收率达87% ~90%. 用毛细管气相色谱法分析了单氰乙基化反应中各组份的含量;所合成的7种N-氰乙基邻位取代苯胺和N-氰乙基间位取代苯胺用DTA-TG、UV、IR、1H NMR和EA进行了物性和结构表征
语种：
中文
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Effect of preparation method on the physical and catalytic property of nanocrystalline Fe2O3
作者：
Wu, Gang;Tan, Xiaoyan;Li, Guiying;Hu, Changwei*
期刊：
Journal of Alloys and Compounds ,2010年504(2):371-376 ISSN：0925-8388
通讯作者：
Hu, Changwei
作者机构：
[Hu, Changwei; Tan, Xiaoyan; Wu, Gang; Li, Guiying] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China.;[Wu, Gang] SW Jiaotong Univ Emei, Dept Basic Courses, Emei 614202, Sichuan, Peoples R China.;[Tan, Xiaoyan] Cent S Univ Forestry & Technol, Inst Appl Chem, Changsha 412006, Hunan, Peoples R China.
通讯机构：
[Hu, Changwei] S;Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China.
关键词：
Catalytic properties;Fourier transform infrared;Hydroxylation of benzene;Nanocrystallines;Powder X ray diffraction;Precipitation methods;Preparation method;SEM;Surface oxygen;Thermal decompositions;XPS;Benzene;Benzene refining;Catalysis;Fourier transforms;Hydrogen peroxide;Infrared spectroscopy;Nanostructured materials;Oxygen;Phenols;Photoresists;Precipitation (chemical);Pyrolysis;Reaction kinetics;Scanning electron microscopy;Wavelet transforms;X ray diffraction;X ray photoelectron spectroscopy;X rays;Crystal structure
摘要：
Nanocrystalline Fe<inf>2</inf>O<inf>3</inf> was prepared by five different methods. The samples were characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). It is found that pure single-phase of α-Fe<inf>2</inf>O<inf>3</inf> crystal could be gained via thermal decomposition and ultrasonic-precipitation method, while both α-Fe <inf>2</inf>O<inf>3</inf> and γ-Fe<inf>2</inf>O<inf>3</inf> are obtained by the other methods. The morphologies and particle sizes of the samples obtained are approximate except that by thermal decomposition. Compared to α-Fe<inf>2</inf>O<inf>3</inf>, γ-Fe<inf>2</inf>O<inf>3</inf> possesses more surface oxygen species "O<sup>-</sup>". The activity test indicates that surface oxygen species "O<sup>-</sup>" plays a crucial role in the hydroxylation of benzene to phenol with hydrogen peroxide as oxidant. ©2010 Published by Elsevier B.V.
语种：
英文
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水中痕量苯酚的微波萃取气相色谱分析
作者：
谭晓燕;黎国兰;李松;赵莹
期刊：
化学研究与应用 ,2009年21(7):1067-1069 ISSN：1004-1656
作者机构：
[谭晓燕; 赵莹] 中南林业科技大学应用化学研究所;[黎国兰; 李松] 四川绵阳师范学院化学与化学工程系
关键词：
气相色谱法;微波萃取;苯酚
摘要：
水中苯酚的测定是环境检测的一项常规指标.其测定方法有分光光度法、高效液相色谱法和气相色谱法.
语种：
中文
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毛细管气相色谱法测定N-氰乙基-邻氯苯胺的研究
作者：
赵莹;杨志;谭晓燕;文瑞芝
作者机构：
中南林业科技大学应用化学研究所,湖南株洲,412006
会议名称：
第十七届全国色谱学术报告会
会议时间：
2009-04-19
会议地点：
长沙
会议论文集名称：
第十七届全国色谱学术报告会论文集
关键词：
毛细管;气相色谱;N-氰乙基邻氯苯胺
摘要：
建立了测定N-氰乙基-邻氯苯胺的毛细管气相色谱法。采用30m×φ0.32mm×0.5μm SE-30毛细管色谱柱,FID检测器,柱温为250℃,进样口温度为280℃,检测器温度为280℃,载气为氮气,流量25mL/min,分流比1：4,H2流量为30mL/min,Air流量为400mL/min。该法线性范围0.04～2.00mg/mL,回归方程为Y=0.7223X-0.0433,相关系数r=0.9991。相对标准偏差1.82％(c=0.6m∥mL,n=lO),检出限5μg/mL,加标回收率为97.1％～102.0％。
语种：
中文
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AlCl_3催化对位取代苯胺与丙烯腈加成反应的研究
作者：
Zhao Ying* ;Ye Cuiceng;Tan Xiaoyan;Yang Zhi
期刊：
有机化学 ,2009年29(4):643-647 ISSN：0253-2786
通讯作者：
Zhao Ying
作者机构：
[Tan Xiaoyan; Zhao Ying; Ye Cuiceng; Yang Zhi] Cent S Univ Forestry & Technol, Inst Appl Chem, Zhuzhou 412006, Peoples R China.
通讯机构：
[Zhao Ying] C;Cent S Univ Forestry & Technol, Inst Appl Chem, Zhuzhou 412006, Peoples R China.
关键词：
N-氰乙基对位取代苯胺;NN-二氰乙基对位取代苯胺
摘要：
报道了无水AlCl3催化5种对位取代苯胺与丙烯腈发生Michael加成反应生成相应的N-氰乙基对位取代苯胺、N,N-二氰乙基对位取代苯胺,结果表明,AlCl3对该类反应具有很高的催化活性.在丙烯腈稍过量、较低温度、少量AlCl3催化剂的催化下,主要生成N-氰乙基对位取代苯胺,收率达88%～90%;在丙烯腈过量较多、75～85℃及较多AlCl3催化剂的催化下,主要生成N,N-二氰乙基对位取代苯胺,收率达88%～91%.当加入Lewis碱NaOAc作助催化剂时有利于提高N-氰乙基对位取代苯胺的选择性和收率;当加入Lewis酸ZnCl2作助催化剂时则有利于提高N,N-二氰乙基对位取代苯胺的选择性和收率.并对合成的5种N,N-二氰乙基对位取代苯胺用TG-DTA,UV,IR,NMR和元素分析进行了物性和结构表征.
语种：
中文
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微波萃取-柱前衍生-气相色谱法测定水中痕量苯酚
作者：
谭晓燕;黎国兰;李松;赵莹;王娟
期刊：
理化检验-化学分册 ,2009年45(1):32-34 ISSN：1001-4020
作者机构：
[谭晓燕; 赵莹] 中南林业科技大学应用化学研究所;[黎国兰; 李松; 王娟] 四川绵阳师范学院化学与化学工程系;吉林省电子信息技术学院
关键词：
微波加热萃取;气相色谱法;柱前衍化法;苯酚;水样
摘要：
含痕量苯酚的水样与丙酮和环己烷(1+1)的混合溶剂混合,置于控温在60℃的微波炉中加热30 s,使苯酚萃取进入有机相,分取部分萃取液在pH 8～9的条件下与衍生试剂乙酸酐反应15 min,所生成的苯酚衍生物用石油醚萃取,分取部分经脱水后的有机相进样作气相色谱分析.色谱测定中采用DB-17毛细管色谱柱(30 m×0.53 mm,1.0μm)及氢火焰离子化检测器,在优化的条件下测得方法的检出限(3S/N)为0.01 mg·L~(-1).按所提出方法分析了8个模拟水样,根据测得苯酚的含量值算得其相对标准偏差为4.2%,并按标准加入法求得其平均回收率为94.0%.
语种：
中文
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