作者机构：
[Yufei Wu; Kelin Li; Xiaohua Fu] College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan, 410004, China
通讯机构：
[Yufei Wu] C;College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan, 410004, China
关键词：
Data envelopment analysis;Zero-sum game;Quality function deployment;Carbon emissions;Carbon reduction;Allowance allocation
摘要：
As the global economic environment changes, the concept of green and sustainable development has become the international community’s consensus. As a participant in the worldwide emission reduction plan, China is also under great pressure to reduce carbon emissions. As an example, this study constructs an optimal scheme for regional carbon emission allowance allocation in Hunan Province, China. We first forecast the total carbon emissions in 2030 for each city, state, and major industry in Hunan Province through a scenario and then innovatively use the mass function allocation theory in marketing to sort out the logical ideas of the optimization model. More importantly, we combine the zero-sum game theory to build the zero-sum game-data envelopment analysis model to continuously reallocate the carbon emission allowances of each city and state and major industries in Hunan Province until the optimal allocation scheme is reached. From the perspective of each city and state, the initial carbon emission efficiency level of fourteen cities in Hunan is high, but there are still some differences. From the perspective of industries, the initial efficiency of carbon emission of six major industries in Hunan is lower, and the difference in efficiency values is evident.
作者机构：
[王小利] Agricultural College of Guizhou University, Guiyang, 550025, China;[李宇虹; 吴金水; 葛体达; 祝贞科] Key Laboratory of Agro Ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha, 410125, China;[李科林] School of Environmental Science and Engineering, Central South Forestry University, Changsha, 410004, China;[江家彬] Agricultural College of Guizhou University, Guiyang, 550025, China, Key Laboratory of Agro Ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha, 410125, China;[林森] Key Laboratory of Agro Ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha, 410125, China, School of Environmental Science and Engineering, Central South Forestry University, Changsha, 410004, China
通讯机构：
[Wang, X.] A;[Zhu, Z.] K;Agricultural College of Guizhou UniversityChina;Key Laboratory of Agro Ecological Processes in Subtropical Region, China
作者机构：
[林森; 李科林] School of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha;410004, China;[肖谋良; 魏亮; 刘守龙; 祝贞科; 葛体达; 吴金水] Key Laboratory of Subtropical Agro-Ecological Processes, Institute of Subtropical Agro-Ecology, Chinese Academy of Sciences, Changsha;410125, China;[江家彬] College of Agriculture, Guizhou University, Guiyang
作者机构：
[柏菁; 李奕霏; 李科林; 彭佩钦] College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha;410004, China;[刘守龙; 祝贞科; 葛体达; 吴金水] Key Laboratory of Agro-Ecological Processes in Subtropical Regions, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha;410125, China;[吴小红] College of Life Science and Technology, Central South University of Forestry and Technology, Changsha
摘要：
Verticillium insectorum J3 was isolated from a local lead-zinc deposit tailing, and its biosorption characteristics and reaction to the toxicities of different Pb(II) and Zn(II) concentrations were investigated. SEM, FTIR, a pH test and a desorption experiment were carried out to identify a possible mechanism. The biosorption of J3 presented an inhibition trend at low concentrations (25-75 mg L-1) and promotion at high concentrations (100-300 mg L-1). J3 absorbed Pb(II) prior to Zn(II) and produced alkaline substances, while mycelial and pellet morphology modifications were important for the removal of Pb(II) and Zn(II) under different stressful conditions (SEM results). Both intracellular accumulation and extracellular absorption may contribute to the removal of Pb(II) at lower concentrations (25-50 mg L-1), although mainly extracellular biosorption occurred at higher concentrations (75-300 mg L-1). However, Zn(II) bioaccumulation occurred at all concentrations assayed. Verticillium insectorum J3 may have evolved active defenses to alleviate the toxicity of heavy metals and proved to be a highly efficient biosorbent, especially for Pb(II) at high concentrations. This study is a useful reference for the development of biotreatment technologies to mitigate heavy metal waste.
作者机构：
[舒艳; 李芸; 李科林; 汤春芳] College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha, 410004, China
通讯机构：
[Tang, C.] C;College of Environmental Science and Engineering, China
摘要：
In this study, Salix matsudana activated carbon (SAC) was prepared by phosphoric acid activation, and the adsorption characteristics of Cd(II) and Pb(II) on SAC in single-and double-component solutions were investigated. In both systems, the adsorption capacities of both ions on SAC increased with the increasing initial pH value and temperature in the solutions, and the adsorption equilibrium was approached at 10 min. The adsorption process was spontaneous, endothermic, and depicted well by the pseudo-second-order adsorption model, and the equilibrium adsorption fitted reasonably well with the Langmuir isotherm. The maximum adsorption capacity (Q(m)) of Cd(II) and Pb (II) was 58.48 and 59.01 mg/g, respectively, in the single-element systems. However, it reduced to 25.32 and 31.09 mg/g, respectively, in the double-element system. The physicochemical property analysis showed that the specific surface area, total pore volume, and average pore diameter of SAC was 435.65 m(2)/g, 35.68 mL/g, and 3.86 nm, respectively. The SAC contained groups of -OH, C=O, and P=O. Results suggest that SAC had a good performance for the adsorption of Cd(II) and Pb(II) from solution, and the adsorption selectivity sequence was Pb(II) > Cd(II).
作者机构：
[宋金风; 李科林; 汤春芳; 舒艳; 李冰] College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha, 410004, China
通讯机构：
[Tang, C.] C;College of Environmental Science and Engineering, China
