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Self-assembling behavior of cellulose nanoparticles during freeze-drying: Effect of suspension concentration, particle size, crystal structure, and surface charge

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成果类型:
期刊论文
作者:
Han, Jingquan;Zhou, Chengjun;Wu, Yiqiang;Liu, Fangyang;Wu, Qinglin*
通讯作者:
Wu, Qinglin
作者机构:
[Han, Jingquan; Wu, Qinglin; Zhou, Chengjun] Louisiana State Univ AgCtr, Sch Renewable Nat Resources, Baton Rouge, LA 70803 USA.
[Wu, Yiqiang] Cent South Forestry Univ Sci & Technol, Coll Mat Sci & Engn, Changsha, Peoples R China.
[Liu, Fangyang] Louisiana State Univ, Dept Phys & Astron, Baton Rouge, LA 70803 USA.
通讯机构:
[Wu, Qinglin] L
Louisiana State Univ AgCtr, Sch Renewable Nat Resources, Baton Rouge, LA 70803 USA.
语种:
英文
期刊:
Biomacromolecules
ISSN:
1525-7797
年:
2013
卷:
14
期:
5
页码:
1529-1540
基金类别:
Louisiana Board of Regents [LEQSF-EPS(2013)-PFUND-318, (LEQSF(2010-13)-RD-B-01]; Chinese Scholarship Council (CSC)China Scholarship Council [2009660015]
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
Cellulose nanocrystals and cellulose nanofibers with I and II crystalline allomorphs (designated as CNC I, CNC II, CNF I, and CNF II) were isolated from bleached wood fibers by alkaline pretreatment and acid hydrolysis. The effects of concentration, particle size, surface charge, and crystal structure on the lyophilization-induced self-assembly of cellulose particles in aqueous suspensions were studied. Within the concentration range of 0.5 to 1.0 wt %, cellulose particles self-organized into lamellar structured foam composed of aligned membran...

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