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Photoluminescence of Eu2+, Ce3+and Tb3+in a new potassium barium phosphate K2Ba3(P2O7)2host lattice

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成果类型:
期刊论文
作者:
Meng, Fangui;Zhang, Xinmin*;Xu, Yang;Yang, Jiaxin;Cheng, Zhe
通讯作者:
Zhang, Xinmin
作者机构:
[Xu, Yang; Cheng, Zhe; Meng, Fangui; Yang, Jiaxin; Zhang, Xinmin] Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Zhang, Xinmin] C
Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Crystal structure;Emission spectroscopy;Energy transfer;Europium;Phosphors;Photoluminescence;Supercomputers;Barium phosphate;Deep-blue emissions;Emission spectrums;Excitation wavelength;Forbidden transitions;High temperature;K2Ba3(P2O7)2;Solid-state synthesis;Cerium
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2017
卷:
729
页码:
724-729
基金类别:
The project was sponsored by the Technology Program of Environmental Protection Department of Hunan (No. 2013-312 ). The project was also supported by the Geology Exploration Foundation of Hunan Province Department of Land & Resources, China.
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
The Eu2+, Ce3+, Tb3+ and Ce3+-Tb3+ doped ternary metal diphosphate K2Ba3(P2O7)2 is prepared using high temperature solid state synthesis. K2Ba3(P2O7)2:Eu2+ shows a deep blue emission (λmax = 405 nm) when it is excited by UV lights. The broad peak at 405 nm can be decomposed to two Gaussian curves with maxima at 405 and 440 nm which can be attributed to the presence of two crystallographically different Eu2+ sites in the crystal structure. The emission spectrum of K2Ba3(P2O7)2:Ce3+ is dependent of the excitation wavelength that also results fro...

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