Hunan Provincial Innovation Foundation for Postgraduate; Scientific Research Fund of Hunan Provincial Education Department [21B0262, 22B1094]; Natural Science Foundation of Hunan Province [2022JJ40857]; [CX20230757]
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
An alkyl radical initiated cyclization/tandem reaction of alkyl bromides and K2S2O5 with alkyl electrophiles is developed for the synthesis of various lactam‐substituted alkyl sulfones in a metal‐free catalytic system. Comprehensive Summary An alkyl radical initiated cyclization/tandem reaction of alkyl bromides and alkyl electrophiles by using potassium metabisulphite (K2S2O5) as a connector is developed for the synthesis of various lactam‐substituted alkyl sulfones. Notably, this process does not require a metal catalyst or metal powder re...