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Moisture adsorption in TEMPO-oxidized cellulose nanocrystal film at the nanogram level based on micro-FTIR spectroscopy

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成果类型:
期刊论文
作者:
Yuan, Hanmeng;Guo, Xin*;Xiao, Teng;Ma, Qiang;Wu, Yiqiang
通讯作者:
Guo, Xin
作者机构:
[Ma, Qiang; Guo, Xin; Yuan, Hanmeng] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Hunan, Peoples R China.
[Wu, Yiqiang; Xiao, Teng] Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Guo, Xin] C
Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Cellulose nanocrystal film;Quantitative prediction model;Moisture adsorption;Micro-FTIR spectroscopy
期刊:
Cellulose
ISSN:
0969-0239
年:
2019
卷:
26
期:
12
页码:
7175-7183
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [31890771, 31500475]; Natural Science Foundation of Hunan Province, ChinaNatural Science Foundation of Hunan Province [2019JJ50981]; Research Foundation of Education Bureau of Hunan Province, China [18A166]; College Student's Research Learning and Innovative Experiment Project of Central South University of Forestry and Technology [91]
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
理学院
摘要:
The adsorbed water is known to have a significant influence on physical property of cellulose nanocrystal film. In order to characterize moisture adsorption of TEMPO oxidized cellulose nanocrystal film (TOCNF), a strategy for quantitative evaluation of moisture adsorption in TOCNF at the nanogram level is proposed here. In this approach, TOCNF spectra were in situ measured in a large range of relative humidity. Spectral analysis was applied to these measured spectra, and then moisture adsorption sites and spectrum ranges affected by moisture ad...

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