Development of novel sulf-functionalized porous organic polymers (POPs) for Mercury (II) (Hg(2+)) removal is of great significant, but the adsorbents always suffered by the low adsorption capacity, stability, and efficiency for the reason that the common construction of functionalized POPs from the functionalized monomers or post-functionalization of the POPs always sacrifice the porosity. In this paper, porphyrin-based POPs with different heteroatoms were constructed through the aldehyde monomer (benzene, 2,5-thiophenedicarboxaldehyde and thieno[3,2-b]thiophene-2,5-dicarboxaldehyde) and pyrro...