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Stable fluorinated 3D isoreticular nanotubular triazole MOFs: synthesis, characterization and CO2 separation

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成果类型:
期刊论文
作者:
Chen, Sha;Wang, Da-Wei;Wang, Su-Juan*;Jiang, Ji-Jun*;Su, Cheng-Yong
通讯作者:
Wang, Su-Juan;Jiang, Ji-Jun
作者机构:
[Chen, Sha; Su, Cheng-Yong; Wang, Su-Juan; Wang, SJ; Jiang, Ji-Jun; Wang, Da-Wei] Sun Yat Sen Univ, Lehn Inst Funct Mat, Sch Chem, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China.
[Chen, Sha] Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Hunan Prov Key Lab Mat Surface & Interface Sci &, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Wang, SJ; Jiang, JJ] S
Sun Yat Sen Univ, Lehn Inst Funct Mat, Sch Chem, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China.
语种:
英文
关键词:
Functionalized porous MOFs;3D isoreticular triazole MOFs;CO2 separation
期刊:
Journal of Porous Materials
ISSN:
1380-2224
年:
2019
卷:
26
期:
6
页码:
1573-1579
基金类别:
NSFCNational Natural Science Foundation of China [21821003, 21890380, 21890382, 21801252, 21720102007, 21771197]; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01C161]; STP Project of Guangzhou [201607010378]
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
Much of the efficient efforts have been largely devoted to enhancing the CO2 binding affinity in MOFs. In this paper, three isoreticular triazolate frameworks with the formula LIFM-1(TAZ).solvents, LIFM-1(MTAZ).solvents and LIFM-1(AmTAZ).solvents (TAZ = 1,2,4-triazole; MTAZ = 3-methyl-1H-1,2,4-triazole; AmTAZ = 3-amino-1H-1,2,4-triazole) have been prepared by using divalent zinc ions with the ligands of TAZ and its amino and methyl substituted derivatives for comparison of their sorption properties. High thermal stability and phase purity of the three MOFs were verified by thermogravimetric an...

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