A novel visible-light responsive photocatalytic fuel cell with a highly efficient BiVO4/WO3 inverse opal photoanode and a MnO2/graphene oxide nanocomposite modified cathode
Key Research and Development Projects of Hunan Province [2016SK2030]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51508420, 21707169]; National Key Research and Development Projects of China [2016YFD0800805-4]; Guangdong Provincial Natural Science Foundation of ChinaNational Natural Science Foundation of Guangdong Province [2015A030313641, 2017A030313319]; Characteristics Innovation Project of Guangdong Provincial Education Department [2014KTSCX133]; "Thousand-Hundred-Ten" Talents Training Plan of Guangdong Province [S20143558425]; Youth Science Foundation of Wuyi University [2014ZK03]
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
环境科学与工程学院
摘要:
A highly efficient inverse-opal structured BiVO4/WO3 photoanode and a MnO2/graphene oxide (GO) nanocomposite modified cathode were successfully synthesized in this paper. The optimized BiVO4/WO3 inverse opal photoanode achieved a photocurrent density of similar to 5.04 mA/cm(2) at 1.2 V vs. Ag/AgCl under simulated AM 1.5 illumination, which was 2.84 and 2.36 times higher than that of WO(3 )inverse opal photoanode and BiVO4/WO3 nanoflake photoanode, respectively. The BiVO4/WO3 inverse opal photoanode was coupled with the MnO2/GO modified cathode to build up a novel visible-light responsive phot...