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Revealing the Adsorption Mechanisms of Methanol on Lithium-Doped Porous Carbon through Experimental and Theoretical Calculations

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成果类型:
期刊论文
作者:
Luo, Yiting;Fang, Muaoer;Wang, Hanqing;Dai, Xiangrong;Su, Rongkui;...
通讯作者:
Ma, XC;Su, RK
作者机构:
[Luo, Yiting] Hunan First Normal Univ, Changsha 410114, Peoples R China.
[Fang, Muaoer; Ma, Xiancheng] Cent South Univ Forestry & Technol, Coll Mech & Elect Engn, Changsha 410004, Peoples R China.
[Wang, Hanqing; Su, Rongkui; Su, RK] Cent South Univ Forestry & Technol, Coll Environm Sci & Engn, Changsha 410004, Peoples R China.
[Dai, Xiangrong; Su, Rongkui; Su, RK] PowerChina Zhongnan Engn Corp Ltd, Changsha 410004, Peoples R China.
通讯机构:
[Su, RK ; Ma, XC ] C
Cent South Univ Forestry & Technol, Coll Mech & Elect Engn, Changsha 410004, Peoples R China.
Cent South Univ Forestry & Technol, Coll Environm Sci & Engn, Changsha 410004, Peoples R China.
PowerChina Zhongnan Engn Corp Ltd, Changsha 410004, Peoples R China.
语种:
英文
关键词:
porous carbon;methanol adsorption;lithium doping;pore structure;adsorption mechanism
期刊:
Nanomaterials
ISSN:
2079-4991
年:
2023
卷:
13
期:
18
页码:
2564-
基金类别:
Conceptualization, Y.L. and X.M.; methodology, M.F. and R.S.; formal analysis, Y.L. and M.F.; investigation, Y.L. and R.S.; resources, R.S.; data curation, Y.L. and R.S.; writing—original draft preparation, Y.L. and M.F.; writing—review and editing, X.M., X.D. and H.W. and R.S; supervision, X.D. and H.W.; Validation, X.D. and H.W.; project administration, R.S. and X.M.; funding acquisition, R.S., Y.L. and X.M. All authors have read and agreed to the published version of the manuscript. This research was funded by the Major Program Natural Science Foundation of Hunan Province of China (2021JC0001), the National Nature Science Foundation of China (52000183), the Hunan Provincial Natural Science Foundation of China (2023JJ31010), the National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund (ES202380056), a research project funded by the Education Department of Hunan Province (22B0883), the Scientific Research Foundation for Talented Scholars of CSUFT University (2019YJ019, 2020YJ010), the Excellent Youth Fund Project of Hunan Provincial Education Department (21B0248), and the Natural Science Foundation of Changsha (kq220815).
机构署名:
本校为通讯机构
院系归属:
机电工程学院
环境科学与工程学院
摘要:
Previous reports have shown that it is difficult to improve the methanol adsorption performance of nitrogen and oxygen groups due to their low polarity. Here, we first prepared porous carbon with a high specific surface area and large pore volume using benzimidazole as a carbon precursor and KOH as an activating agent. Then, we improved the surface polarity of the porous carbon by doping with Lithium (Li) to enhance the methanol adsorption performance. The results showed that the methanol adsorption capacity of Li-doped porous carbon reached 35.4 mmol g(-1), which increased by 57% compared to ...

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