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Achieving Ultrahigh Energy Density and Long Durability in a Flexible Rechargeable Quasi-Solid-State Zn–MnO2Battery

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成果类型:
期刊论文
作者:
Zeng, Yinxiang;Zhang, Xiyue;Meng, Yue;Yu, Minghao;Yi, Jianan;...
通讯作者:
Lu, Xihong;Wu, Yiqiang
作者机构:
[Zhang, Xiyue; Yu, Minghao; Tong, Yexiang; Zeng, Yinxiang; Meng, Yue; Lu, Xihong] Sun Yat Sen Univ, Sch Chem, Key Lab Bioinorgan & Synthet Chem KLGHEI Environm, MOE, Guangzhou 510275, Guangdong, Peoples R China.
[Wu, Yiqiang; Yi, Jianan] Cent South Univ Forestry & Technol, Hunan Prov Collaborat Innovat Ctr High Efficiency, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Lu, Xihong] S
[Wu, Yiqiang] C
Sun Yat Sen Univ, Sch Chem, Key Lab Bioinorgan & Synthet Chem KLGHEI Environm, MOE, Guangzhou 510275, Guangdong, Peoples R China.
Cent South Univ Forestry & Technol, Hunan Prov Collaborat Innovat Ctr High Efficiency, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Zn-MnO2 batteries;durability;flexible;rechargeable;ultrahigh energy density
期刊:
Advanced Materials
ISSN:
0935-9648
年:
2017
卷:
29
期:
26
页码:
1700274-
基金类别:
The authors acknowledge the financial support of this work received by the National Natural Science Foundation of China (Grant Nos. 21403306, 2016YFA0202604, and 31530009), Guangdong Natural Science Funds for Distinguished Young Scholar (Grant No. 2014A030306048), Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program (Grant No. 2015TQ01C205), Technology Planning Project of Guangdong Province (Grant No. 2015B090927007), and the Pearl River Nova Program of Guangzhou (Grant No. 201610010080). Note: The article was corrected after an editorial error on initial publication online to make it clear that the article refers to Zn?MnO2 batteries.
机构署名:
本校为通讯机构
院系归属:
材料科学与工程学院
摘要:
Advanced flexible batteries with high energy density and long cycle life are an important research target. Herein, the first paradigm of a high-performance and stable flexible rechargeable quasi-solid-state Zn–MnO2 battery is constructed by engineering MnO2 electrodes and gel electrolyte. Benefiting from a poly(3,4-ethylenedioxythiophene) (PEDOT) buffer layer and a Mn2+-based neutral electrolyte, the fabricated Zn–MnO2@PEDOT battery presents a remarkable capacity of 366.6 mA h g−1 and good cycling performance (83.7% after 300 cycles) in aque...

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