Dual-engine-driven synthesis of unsaturated esters over channel-expanding Cu–Cs catalysts

认领

导出

Link by DOI

反馈

作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Fan, Jiaqi;Shao, Lishu*;Gao, Weizhe;Han, Yitong;Xiang, Wenjie;...

通讯作者：

Yu, ZX;Shao, Lishu;Yang, Guohui;Tsubaki, N;Shao, LS;Yang, GH;Zhang, PP

作者机构：

[Fan, Jiaqi; Yu, Zhixin] Shaoxing Univ, Inst New Energy, Sch Chem & Chem Engn, Shaoxing 312000, Peoples R China.

[Liu, Chufeng; Liu, Zhihao; Fan, Jiaqi; Yang, Guohui; Shao, Lishu; Yasuda, Shuhei; Gao, Weizhe; Shao, LS; Tsubaki, Noritatsu; Han, Yitong; Wang, Bo; Huang, Hao; Xiang, Wenjie] Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan.

[Shao, LS; Shao, Lishu] Cent South Univ Forestry & Technol, Minist Forestry Bioethanol Res Ctr, Sch Mat Sci & Engn, Changsha 410004, Peoples R China.

[Wang, Kangzhou] Ningxia Univ, Sch Mat & New Energy, Yinchuan 750021, Ningxia, Peoples R China.

[Liu, Guangbo] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China.

通讯机构：

[Yang, GH ] D

[Tsubaki, N ; Yang, GH; Shao, LS] U

[Zhang, PP ; Shao, LS ] C

[Yu, ZX ] S

Shaoxing Univ, Inst New Energy, Sch Chem & Chem Engn, Shaoxing 312000, Peoples R China.

语种：

英文

期刊：

CHEMICAL SCIENCE

ISSN：

2041-6520

年：

2025

卷：

期：

页码：

12927-12940

DOI：

10.1039/d5sc02896e

基金类别：

Japan Science & Technology Agency [JPMJSP2145]; JST SPRING [2024RC3195]; Science and Technology Innovation Program of Hunan Province [23B0241]; Research Foundation of Education Bureau of Hunan Province [2025JJ50095]; Nature Science Foundation of Hunan Province

机构署名：

本校为通讯机构

院系归属：

材料科学与工程学院

生命科学与技术学院

摘要：

This study presents a one-step catalytic synthesis of unsaturated esters (methyl acrylate, MA; methyl methacrylate, MMA) from methanol (MeOH, C1 source) and methyl acetate (MAc) via a Cu–Cs dual-engine-driven (DED) system that integrates four sequential steps—dehydrogenation, aldol condensation, hydrogenation, and secondary aldol condensation. The Cu-engine facilitates proton transfer by capturing protons during MeOH dehydrogenation and donating them in methyl acrylate (MA) hydrogenation, while the Cs-engine activates saturated esters for for...

反馈

产权有误：本人成果被他人认领

数据有误：数据基本信息有误

归属有误：成果的院系归属、机构署名归属有误

其他原因：

验证码：

看不清楚，换一个

确定

取消

成果认领

标题：

用户	作者	通讯作者	--
	请选择	请选择	--

确定

取消

Dual-engine-driven synthesis of unsaturated esters over channel-expanding Cu–Cs catalysts

反馈

成果认领

提示

该栏目需要登录且有访问权限才可以访问