The construction of oxygen reduction reaction (ORR) electrocatalysts with well-textured structure and desirable activity remains great challenge for the complicated procedures and poor interface. Herein, inspired by sea anemones, the highly ordered Co-based carbon nanotubes electrocatalysts were elaborately assembled on wood fibers via stoichiometry. The porous cell-wall and abundant oxygen groups in lignocellulosic scaffold impose such preferable structure, in which the Co-based carbon nanotubes with Co single atoms and Co nanoparticles were tuned to possess higher catalytic activity and capt...