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Biomimetic mineralization of the carbonates regulated by using hydroxypropyl methylcellulose macromolecules as organic templates

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成果类型:
期刊论文
作者:
Yang, Tianli;He, Ren;Omeoga, Uche;Wang, Lin;Sun, Renrui;...
通讯作者:
Wang, Wenlei
作者机构:
[Wang, Wenlei; Omeoga, Uche; Yang, Tianli; He, Ren; Zhang, Ning] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Hunan, Peoples R China.
[Sun, Renrui; Wang, Lin] Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Xu, Dong] Cent South Univ Forestry & Technol, Sch Food Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Zeng, Dewen] Cent S Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China.
通讯机构:
[Wang, Wenlei] C
Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Binding energy;Biomimetics;Calcite;Calcium carbonate;Carbonate minerals;Carbonates;Carbonation;Mineralogy;Morphology;Polymorphism;Biomimetic mineralization;Crystal growth mechanism;HPMC;Hydroxypropyl methylcellulose;Magnesium concentrations;Mineralization process;Molar ratio;Polarizing microscopes;Magnesium compounds
期刊:
Journal of Crystal Growth
ISSN:
0022-0248
年:
2019
卷:
508
页码:
72-81
基金类别:
The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Grant No: 21607176 ), the Natural Science Foundation of Hunan Province, China (Grant No. 2017JJ3516 ), the Research Foundation of Education Bureau of Hunan Province, China (Grant No. 16B274 ), and The Open fund for key discipline of Forestry of Central South University of Forestry and Technology (Grant No. 2016ZD11 ). The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Grant No: 21607176), the Natural Science Foundation of Hunan Province, China (Grant No. 2017JJ3516), the Research Foundation of Education Bureau of Hunan Province, China (Grant No. 16B274), and The Open fund for key discipline of Forestry of Central South University of Forestry and Technology (Grant No. 2016ZD11).
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
食品科学与工程学院
理学院
摘要:
Control of the morphology of carbonate crystals plays an indispensable role in mineralization process. We investigated the relationship between HPMC concentration and different molar ratios of Mg/Ca on the carbonate crystallization by monitoring crystal polymorph, crystal size, and morphology. In this experiment, the total molars of [Mg 2+ ] and [Ca 2+ ] were 50 mM. The results demonstrated that different molar ratio of Ma/Ca primarily can help different morphology form in multidimensional spline space, for instance, lens-like calcite, spindle ...

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