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Bifunctional thiophene-based covalent organic frameworks for Hg2+ removal and I2 vapor adsorption

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成果类型:
期刊论文
作者:
Wang, Lizhi;Liu, Junlong;Wang, Jiajia;Huang, Jianhan
通讯作者:
Wang, LZ;Huang, JH
作者机构:
[Liu, Junlong; Wang, Lizhi] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.
[Wang, Jiajia; Huang, Jianhan] Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Micro & Nano Mat Interface, Changsha 410083, Peoples R China.
通讯机构:
[Wang, LZ ; Huang, JH ] C
Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.
Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Micro & Nano Mat Interface, Changsha 410083, Peoples R China.
语种:
英文
关键词:
Bifunctional;Thiophene;Covalent organic frameworks;Hg2+removal;I2 vapor adsorption
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2023
卷:
473
页码:
145405
基金类别:
Lizhi Wang: Conceptualization, Investigation, Writing – original draft. Junlong Liu: Investigation, Writing – review & editing. Jiajia Wang: Investigation, Writing – review & editing. Jianhan Huang: Supervision, Writing – review & editing, Funding acquisition.
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
Novel bifunctional thiophene-based COFs were constructed according to Schiff base reaction between tetrakis(4-aminophenyl)-ethane and 2,5-thiophenedicarboxaldehyde/ thieno[3;2-b]thiophene-2,5-dicarboxaldehyde. The loading of N/S heteroatoms in the skeleton not only take the COFs abundant functional groups, but also elevate the stability of the functional groups, and avoid the blocking of the pores from the post-functionlization of functional groups. The thiophene-based COFs all showed good crystalline structure, high Brunauer–Emmett–Teller (B...

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