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Molecular association of adsorbed water with lignocellulosic materials examined by micro-FTIR spectroscopy

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成果类型:
期刊论文
作者:
Guo, Xin;Qing, Yan;Wu, Yiqiang*;Wu, Qinglin*
通讯作者:
Wu, Yiqiang;Wu, Qinglin
作者机构:
[Wu, Yiqiang; Wu, Qinglin; Guo, Xin; Qing, Yan] Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Wu, Qinglin] Louisiana State Univ, AgCtr, Sch Renewable Nat Resources, Baton Rouge, LA 70803 USA.
通讯机构:
[Wu, YQ; Wu, QL] C
[Wu, Qinglin] L
Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
Louisiana State Univ, AgCtr, Sch Renewable Nat Resources, Baton Rouge, LA 70803 USA.
语种:
英文
关键词:
Hydrogen-bonding;Hydrophilic groups;Moisture adsorption
期刊:
International Journal of Biological Macromolecules
ISSN:
0141-8130
年:
2016
卷:
83
页码:
117-125
基金类别:
Natural Science Foundations of ChinaNational Natural Science Foundation of China (NSFC) [31530009, 31500475]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2014M562146]; Research Foundation of Education Bureau of Hunan Province [15B256]; Hunan Province Science and Technology Project [2015RS4046]
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
For lignocellulosic materials, water adsorption is extremely important for its product performance. For gaining a deeper understanding of moisture adsorption mechanisms, the molecular interactions between adsorbed water and a typical lignocellulosic material (i.e., wood) were studied using in-situ microscopic Fourier transform infrared (micro-FTIR) spectroscopy and a specially designed sample cell. The spectral shifts of 1733 cm(-1), 1604cm(-1) and 1236 cm(-1) and different spectra between the moist and dry spectra indicated that carbonyl C=O and C-O groups preferred to combine with water mole...

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