National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [31530009]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2016JJ3186]; National Forestry Nonprofit Industry Research of Major Projects [201404604]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [154808]; Youth Foundation of Central South University of Forestry and Technology [QJ201506]
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
The pH- and temperature-responsive chitosan-graft-poly(2-(dimethylamino) ethyl methacrylate) (CS-g-PDMAEMA) were synthesized via atom transfer radical polymerization (ATRP) and evidenced by FTIR spectroscopy. Chitosan macroinitiator (CS-Br) was prepared by phthaloylation of amino groups of chitosan and acylation of hydroxyl groups of chitosan with 2-bromoisobutyryl bromide. The pH and temperature responses of the copolymer micelles were characterized by particle diameter and particle size analyzers. The film prepared from CS-g-PDMAEMA was used as a coating film on the surface of the grape. And...