A facile sol–gel method has been developed to create a superhydrophobic surface on aluminum substrate with tetraethylorthosilicate (TEOS) and vinyltriethoxysilane (VTES) as co-precursor at room temperature. Firstly, nanometer sized silica particles were self assembled on the substrate through the hydrolysis of TEOS. Then, the silica particles were modified with vinylsiloxane through the hydrolysis and condensation polymerization of VTES. The emphasis was focused on investigating the influence of the molar ratio between NH3·H2O and ethanol on ...