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N-doped defective carbon with trace Co for efficient rechargeable liquid electrolyte-/all-solid-state Zn-air batteries

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成果类型:
期刊论文
作者:
Chen, Zhiyan;Wang, Qichen;Zhang, Xiaobin;Lei, Yongpeng*;Hu, Wei;...
通讯作者:
Lei, Yongpeng;Wang, Yaobing
作者机构:
[Wang, Qichen; Chen, Zhiyan] Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Chsangsha 410004, Peoples R China.
[Wang, Qichen] Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China.
[Zhang, Xiaobin] Japan Adv Inst Sci & Technol, Ctr Nano Mat & Technol, 1-1 Asahidai, Nomi, Ishikawa 9231292, Japan.
[Lei, Yongpeng] Cent South Univ, Sch Aeronaut & Astronaut, Changsha 410083, Hunan, Peoples R China.
[Lei, Yongpeng] Cent South Univ, Sci & Technol High Strength Struct Mat Lab, Changsha 410083, Hunan, Peoples R China.
通讯机构:
[Lei, Yongpeng; Wang, Yaobing] C
[Lei, Yongpeng] N
Cent South Univ, Sch Aeronaut & Astronaut, Changsha 410083, Hunan, Peoples R China.
Cent South Univ, Sci & Technol High Strength Struct Mat Lab, Changsha 410083, Hunan, Peoples R China.
Natl Univ Def Technol, Coll Basic Educ, Changsha 410073, Hunan, Peoples R China.
语种:
英文
关键词:
Defect;Oxygen electrocatalysts;Rechargeable all-solid-state batteries
关键词(中文):
空气电池;可充电;液体;碳;热分解过程;力密度;多功能
期刊:
科学通报(英文版)
ISSN:
2095-9273
年:
2018
卷:
63
期:
9
页码:
548-555
基金类别:
The SEM image in Fig. 1a shows that Co-NDC with necklace-like network is composed of disordered and rough carbon nanoparticles with a diameter ranging from 25 to 40 nm. The black Co nanoparticles marked with red circles were observed in the TEM image (Fig. 1b). The elemental mapping images in Fig. 1c further confirm the high dispersion of Co N, O and C species. In addition, the microstructure was further studied by the HRTEM measurement (Fig. 1d). The lattice fringes of 0.205 and 0.36 nm are
机构署名:
本校为第一机构
院系归属:
材料科学与工程学院
摘要:
Simple synthesis of multifunctional electrocatalysts with plentiful active sites from earth-abundant materials is especially fascinating. Here, N-doped defective carbon with trace Co (1.5 wt%) was prepared via a scalable one pot solid pyrolysis process. The sample exhibits efficient bifunctional OER/ORR activity in alkaline, mainly ascribed to the unique micro-mesoporous structure (1–3 nm), high population of graphitic-N doping (up to 49.0%), abundant defects and the encapsulated Co nanoparticles with graphitized carbon. The according recharge...

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