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Cetyltrimethyl ammonium mediated enhancement of the red emission of carbon dots and an advanced method for fluorometric determination of iron(III)

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成果类型:
期刊论文
作者:
Li, Te;Xie, Lianwu;Long, Ruiqing;Tong, Chaoying;Guo, Ying;...
通讯作者:
Shi, Shuyun;Lin, Qinlu
作者机构:
[Shi, Shuyun; Tong, Chaoying; Tong, Xia; Li, Te; Long, Ruiqing] Cent S Univ, Coll Chem & Chem Engn, Key Lab Hunan Prov Water Environm & Agr Prod Safe, Changsha 410083, Hunan, Peoples R China.
[Shi, Shuyun; Shi, SY; Lin, Qinlu; Xie, Lianwu] Cent South Univ Forestry & Technol, Coll Sci, Coll Food Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Shi, Shuyun; Guo, Ying] Cent S Univ, Xiangya Hosp, Dept Clin Pharmacol, Hunan Key Lab Pharmacogenet, Changsha 410078, Hunan, Peoples R China.
通讯机构:
[Shi, Shuyun; Shi, SY; Lin, QL] C
Cent S Univ, Coll Chem & Chem Engn, Key Lab Hunan Prov Water Environm & Agr Prod Safe, Changsha 410083, Hunan, Peoples R China.
Cent South Univ Forestry & Technol, Coll Sci, Coll Food Sci & Engn, Changsha 410004, Hunan, Peoples R China.
Cent S Univ, Xiangya Hosp, Dept Clin Pharmacol, Hunan Key Lab Pharmacogenet, Changsha 410078, Hunan, Peoples R China.
语种:
英文
关键词:
Fluorometric assay;Human plasma;Metal ion;Nanomaterial;Quenching mechanism;Surface functionalization;Surfactant
期刊:
Microchimica Acta
ISSN:
0026-3672
年:
2019
卷:
186
期:
12
页码:
791
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China [31660181]; Hunan Provincial Science and Technology Department [2018JJ1043]; Key Laboratory of Hunan Province for Water Environment and Agriculture Product Safety [2018TP1003]
机构署名:
本校为通讯机构
院系归属:
食品科学与工程学院
理学院
摘要:
Red-emissive carbon dots (CDs) were synthesized by one-step hydrothermal technique using citric acid (CA), and urea in N,N-dimethylformamide (DMF) solution. The CDs has an average diameter of 2.3 nm, excitation/emission maxima at 553/606 nm, and a low photoluminescence quantum yield (4%). Fluorescence is weakly quenched by the ions Fe(3+), Hg(2+), Cu(2+), Co(2+), Zn(2+), Ca(2+), Ni(2+), and Pb(2+). After addition of cetyltrimethyl ammonium ion (CTAB), electrostatic interaction between negatively charged CDs and CTAB causes the CDs to self-aggregate. The formation of CD/CTAB increases the avera...

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