NSFCNational Natural Science Foundation of China (NSFC) [21202206]; Scientific Innovation Fund for Graduate of Hunan Province [CX2015B298]; Scientific Innovation Fund for Graduate of Central South University of Forestry and Technology [CX2013B16]
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
A new route for the synthesis of 2(5H)-furanones is presented via Pd(PPh3)4-catalyzed cascade reaction of acetlenic acids with iodonium ylides using K2CO3 as the base. The cascade proceeds through dehydrogenation coupling and cyclization under mild conditions.