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Palladium-Catalyzed Dehydrogenation Coupling-Cyclization Reactions of Acetylenic Acids with Iodonium Ylides for the Synthesis of 2(5H)-Furanones

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成果类型:
期刊论文
作者:
Li, Wen-Guang;Cai, Bo;Xiao, Hong-Bo;Pi, Shao-Feng*;Sun, Han-Zhou
通讯作者:
Pi, Shao-Feng
作者机构:
[Li, Wen-Guang; Xiao, Hong-Bo; Pi, Shao-Feng; Sun, Han-Zhou; Cai, Bo] Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Pi, Shao-Feng] C
Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
palladium;dehydrogenation;acetylenic acids;iodonium ylides;2(5H)-furanones
期刊:
SYNLETT
ISSN:
0936-5214
年:
2016
卷:
27
期:
5
页码:
794-798
基金类别:
NSFCNational Natural Science Foundation of China (NSFC) [21202206]; Scientific Innovation Fund for Graduate of Hunan Province [CX2015B298]; Scientific Innovation Fund for Graduate of Central South University of Forestry and Technology [CX2013B16]
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
A new route for the synthesis of 2(5H)-furanones is presented via Pd(PPh3)4-catalyzed cascade reaction of acetlenic acids with iodonium ylides using K2CO3 as the base. The cascade proceeds through dehydrogenation coupling and cyclization under mild conditions.

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