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Color tunable emission from CaS:Cu+, Mn2+ rare-earth-free phosphors prepared by a simple carbon-thermal reduction method

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成果类型:
期刊论文
作者:
Tong, Xubo;Yang, Jiaxin;Wu, Pianpian;Zhang, Xinmin*;Seo, Hyo Jin
通讯作者:
Zhang, Xinmin
作者机构:
[Tong, Xubo; Yang, Jiaxin; Wu, Pianpian; Zhang, Xinmin] Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Hunan Prov Key Lab Mat Surface & Interface Sci &, Changsha 410004, Hunan, Peoples R China.
[Seo, Hyo Jin] Pukyong Natl Univ, Dept Phys, Busan 608737, South Korea.
[Seo, Hyo Jin] Pukyong Natl Univ, Interdisciplinary Program Biomed Mech & Elect Eng, Busan 608737, South Korea.
通讯机构:
[Zhang, Xinmin] C
Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Hunan Prov Key Lab Mat Surface & Interface Sci &, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Calcium compounds;Carbon;Color;Copper compounds;Emission spectroscopy;Energy transfer;Manganese compounds;Phosphors;Photoluminescence;Rare earths;Band emission;Carbon-thermal reduction;Color tunable;Doping concentration;Emission spectrums;Excitation spectrum;Photoluminescence properties;Rare-earth-free;Sulfur compounds
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2019
卷:
779
页码:
399-403
基金类别:
The project was sponsored by the Technology Program of Environmental Protection Department of Hunan (No. 2013-312 ).
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Photoluminescence properties of CaS:Cu+, CaS:Mn2+ and CaS:Cu+, Mn2+ rare-earth -free phosphors prepared by a carbon-thermal reduction method were investigated. The emission spectrum of Cu+-doped CaS consists of two overlapped bands peaking at 415 nm (attributed to isolated Cu+ activator) and 475 nm (attributed to aggregated Cu+ center). The influence of Cu+ doping concentration on the emission spectrum is discussed. The emission spectrum of Mn2+-doped CaS exhibits a band emission peaking at 568 nm under 250 nm excitation. The emission spectra o...

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