The project was sponsored by the Technology Program of Environmental Protection Department of Hunan (No. 2013-312 ).
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Photoluminescence properties of CaS:Cu+, CaS:Mn2+ and CaS:Cu+, Mn2+ rare-earth -free phosphors prepared by a carbon-thermal reduction method were investigated. The emission spectrum of Cu+-doped CaS consists of two overlapped bands peaking at 415 nm (attributed to isolated Cu+ activator) and 475 nm (attributed to aggregated Cu+ center). The influence of Cu+ doping concentration on the emission spectrum is discussed. The emission spectrum of Mn2+-doped CaS exhibits a band emission peaking at 568 nm under 250 nm excitation. The emission spectra o...