In this study, [PW12O40]3− anions have been intercalated into Zn,Al-Layered Double Hydroxides(ZnAl-NO3-LDHs) to synthesize ZnAl-PW12O40-LDHs by ion-exchange reaction. The chemical composition and structure were analyzed by XRD, FT-IR, ICP, and SEM. Then, the nanocellulose based 3D lightweight foam thermal insulation materials was prepared by ZnAl-PW12O40-LDHs and CNF compound with H3BO3. The TG showed that ZnAl-PW12O40- LDHs significantly reduced the maximum decomposition rate and increased the carbon residual rate at 800 °C, which indicated ...