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Heteroatom-doped porous carbons exhibit superior CO2 capture and CO2/N2 selectivity: Understanding the contribution of functional groups and pore structure

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成果类型:
期刊论文
作者:
Ma, Xiancheng;Su, Changqing;Liu, Baogen;Wu, Qingding;Zhou, Ke;...
通讯作者:
Zeng, Zheng;Li, Liqing
作者机构:
[Wu, Qingding; Ma, Xiancheng] Cent South Univ Forestry & Technol, Coll Mech & Elect Engn, Changsha 410004, Hunan, Peoples R China.
[Zhou, Ke; Li, Liqing; Zeng, Zheng; Li, LQ; Su, Changqing; Liu, Baogen] Cent South Univ, Sch Energy Sci & Engn, Changsha 410083, Hunan, Peoples R China.
通讯机构:
[Zeng, Z; Li, LQ] C
Cent South Univ, Sch Energy Sci & Engn, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
Pore structure;Functional groups;Porous carbon;CO2 capture;CO2/N-2 selectivity
期刊:
Separation and Purification Technology
ISSN:
1383-5866
年:
2021
卷:
259
页码:
118065
基金类别:
National Key Technology Support ProgramNational Key Technology R&D Program [2015BAL04B02]; Scientific Research Foundation for Talented Scholars of CSUFT University [2019YJ019]; National Nature Science Foundation ChinaNational Natural Science Foundation of China (NSFC) [21376274]
机构署名:
本校为第一机构
院系归属:
机电工程学院
摘要:
The heteroatom-doped porous carbon is an effective strategy to improve the CO2 uptake. However, there are obvious contradictory conclusions in the previous reports regarding the influences of nitrogen groups and pore sizes. Besides this, previous researches about CO2 capture and CO2/N-2 selectivity on nitrogen-doped carbon materials often ignore the effect of oxygen-containing functional groups. Herein, we successfully synthesized rich oxygen and nitrogen doped carbon materials by hydrothermal treatment using tobacco stem and ethylenediamine, respectively. The obtained porous carbons exhibit h...

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