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Phase transition mechanism of CsPbI2Br perovskite films induced by moisture

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成果类型:
期刊论文
作者:
Liu, Yufei;Lin, Jianting*;Han, Qiang;Yang, Chenggang;Li, Lin;...
通讯作者:
Lin, Jianting;Liu, XL;Yi, RN
作者机构:
[Liu, Yufei; Xiao, Jianrong] Guilin Univ Technol, Coll Phys & Elect Informat Engn, Guilin, Peoples R China.
[Han, Qiang; Lin, Jianting; Yang, Chenggang; Liu, Xiaoliang] Cent South Univ, Sch Phys, Changsha 410083, Peoples R China.
[Li, Lin] Cent South Univ Forestry & Technol, Coll Elect & Informat Engn, Changsha 410004, Peoples R China.
[Yi, Rongnan; Yi, RN] Testing Univ Hunan Prov, Key Lab Food & Environm & Drug Monitoring & Testin, Changsha 410138, Peoples R China.
通讯机构:
[Yi, RN ] T
[Lin, JT; Liu, XL ] C
Cent South Univ, Sch Phys, Changsha 410083, Peoples R China.
Testing Univ Hunan Prov, Key Lab Food & Environm & Drug Monitoring & Testin, Changsha 410138, Peoples R China.
语种:
英文
关键词:
CsPbI2Br perovskite films;solar cells;moisture stability;dual-source co-evaporation;phase transition mechanism
期刊:
Journal of Physics D: Applied Physics
ISSN:
0022-3727
年:
2024
卷:
57
期:
24
页码:
245103
基金类别:
National Natural Science Foundation of Chinahttp://dx.doi.org/10.13039/501100001809 [2022KY0258]; Project for Enhancing Young and Middle-aged Teacher's Research Basis Ability in Colleges of Guangxi [51673217]; National Natural Science Foundation of China [21A0160]; Education Department Key Program of Hunan Province
机构署名:
本校为其他机构
院系归属:
计算机与信息工程学院
摘要:
The humidity stability and phase transition mechanism of the all-inorganic perovskite CsPbI2Br based on an optimized dual-source co-evaporation preparation process are investigated at the film interface level. It is found that the CsPbI2Br films annealed at 300(degrees)C for several minutes exhibit a best crystallinity and photoelectric properties. The as-grown CsPbI2Br film is confirmed to be a alpha phase with a dark brown cubic crystal structure and an average visible transparency of 35.9%. But it will be transformed into its delta phase with a transparent orthorhombic crystal structure and...

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