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Metronidazole Degradation by UV and UV/H2O2 Advanced Oxidation Processes: Kinetics, Mechanisms, and Effects of Natural Water Matrices

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成果类型:
期刊论文
作者:
Su, Rongkui;Dai, Xiangrong;Wang, Hanqing;Wang, Zhixiang;Li, Zishi;...
作者机构:
[Dai, Xiangrong; Su, Rongkui] PowerChina Zhongnan Engn Corp Ltd, Changsha 410004, Peoples R China.
[Luo, Yiting; Su, Rongkui] Hunan First Normal Univ, Changsha 410114, Peoples R China.
[Ouyang, Danxia; Wang, Zhixiang; Su, Rongkui; Wang, Hanqing; Chen, Yonghua; Li, Zishi] Cent South Univ Forestry & Technol, Coll Environm Sci & Engn, Changsha 410004, Peoples R China.
语种:
英文
关键词:
hydroxyl radical;metronidazole;antibiotic;steady-state kinetic model;complex matrix
期刊:
International Journal of Environmental Research and Public Health
ISSN:
1661-7827
年:
2022
卷:
19
期:
19
基金类别:
National Nature Science Foundation of China [52000183]; Key Project of Scientific Research Project of Hunan Provincial Department of Education [20A523]; Central South University of Forestry and Technology Introduced Talent Research Startup Fund [2020YJ010]
机构署名:
本校为其他机构
院系归属:
环境科学与工程学院
摘要:
Advanced oxidation technology represented by hydroxyl radicals has great potential to remove residual antibiotics. In this study, we systematically compared the metronidazole (MTZ) degradation behavior and mechanism in the UV and UV/H2O2 systems at pH 3.00 condition. The results show that the initial reaction rates were 0.147 and 1.47 mu M min(-1) in the UV and UV/H2O2 systems, respectively. The main reason for the slow direct photolysis of MTZ is the relatively low molar absorption coefficient (2645.44 M-1 cm(-1)) and quantum yield (5.9 x 10(-3) mol Einstein(-1)). Then, we measured k(MTZ,cent...

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