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Ammonium Phosphotungstate Bonded on Imidazolized Activated Carbon for Selective Catalytic Rearrangement of α-Epoxypinane to Carveol

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成果类型:
期刊论文
作者:
Zheng, Min;Li, Xiangzhou;Yin, Dulin;Kirk, Steven R.;Li, Hui;...
通讯作者:
Li, XZ;Yin, DL
作者机构:
[Yang, Yanhong; Li, Xiangzhou; Zhou, Peng; Zheng, Min; Li, XZ] Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Changsha 410004, Peoples R China.
[Zheng, Min] Hunan First Normal Univ, Sch Elementary Educ, Changsha 410205, Peoples R China.
[Li, Xiangzhou; Li, XZ] Cent South Univ Forestry & Technol, Inst Nat Prod Proc & Utilizat, Changsha 410004, Peoples R China.
[Yin, Dulin; Kirk, Steven R.] Hunan Normal Univ, Natl & Local Joint Engn Lab New Petro Chem Mat & F, Changsha 410081, Peoples R China.
[Li, Hui] CGS China Geol Survey, Xining Ctr Nat Resources Comprehens Survey, Xining 810008, Peoples R China.
通讯机构:
[Yin, DL ] H
[Li, XZ ] C
Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Changsha 410004, Peoples R China.
Cent South Univ Forestry & Technol, Inst Nat Prod Proc & Utilizat, Changsha 410004, Peoples R China.
Hunan Normal Univ, Natl & Local Joint Engn Lab New Petro Chem Mat & F, Changsha 410081, Peoples R China.
语种:
英文
关键词:
catalytic rearrangement;alpha-epoxypinane;carveol;ammonium phosphotungstate;activated carbon
期刊:
Catalysts
ISSN:
2073-4344
年:
2024
卷:
14
期:
1
页码:
36-
基金类别:
Conceptualization, X.L. and D.Y.; methodology, X.L. and D.Y.; software, M.Z. and P.Z.; resources, X.L. and D.Y.; data curation, M.Z. and H.L.; writing—original draft preparation, M.Z., S.R.K., H.L. and P.Z.; writing—review and editing, M.Z., S.R.K. and Y.Y.; visualization, M.Z. and P.Z.; supervision, M.Z. and H.L.; project administration, M.Z. and X.L.; funding acquisition, D.Y. All authors have read and agreed to the published version of the manuscript. This research was funded by the National Natural Science Foundation of China grant number (22278122) and Key scientific and technological R&D projects in Hunan Province grant number (2015NK3029).
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Carveol is a rare fine chemical with specific biological activities and functions in nature. The artificial synthesis of carveol from plentiful and cheap turpentine is expected to further improve development of pharmaceutical and industrial applications. A new green catalytic system for the preparation of high-value carveol from alpha-epoxypinane is presented. A novel ammonium salt solid acid (AC-COIMI-NH4PW) was obtained from phosphotungstic acid bonded with imidazole basic site on nitrogen-doped activated carbon which, after ammonia fumigation, presented an excellent catalytic performance fo...

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