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Regulation of surface oxygen functional groups and pore structure of bamboo-derived hard carbon for enhanced sodium storage performance

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成果类型:
期刊论文
作者:
Xu, Tianyue;Qiu, Xuan;Zhang, Xiang;Xia, Yongyao
通讯作者:
Zhang, Xiang(zhangxiang@csuft.edu.cn)
作者机构:
[Qiu, Xuan; Xia, Yongyao; Xu, Tianyue] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China.
[Zhang, Xiang] Shanghai PuNa Energy Technol Co Ltd, Shanghai 201512, Peoples R China.
[Zhang, Xiang] Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Hunan Prov Key Lab Mat Surface & Interface Sci & T, Changsha 410004, Peoples R China.
通讯机构:
[Xiang Zhang] S
[Yongyao Xia] D
Department of Chemistry, Fudan University, Shanghai 200433, China<&wdkj&>Shanghai PuNa Energy Technology Co., Limited, Shanghai 201512, China<&wdkj&>College of Materials Science and Engineering, Hunan Province Key Laboratory of Materials Surface & Interface Science and Technology, Central South University of Forestry and Technology, Changsha 410004, China
语种:
英文
关键词:
Bamboo;Carbonyl group;Closed micropore;Hard carbon;Sodium-ion battery;Temperature
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2023
卷:
452
页码:
139514
基金类别:
In summary, carbonyl groups and closed micropores are together introduced into bamboo-derived hard carbon materials combining acid pre-treatment and two-step carbonization method and regulated by carbonization temperature. Carbonyl groups can provide extra active sites which are beneficial for reversible sodium adsorption in the sloping region while the closed microvoids promote sodium ion storage in the plateau region. With the increase of carbonization temperature, the reductions of defects
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
Hard carbon materials with long low-voltage plateau have been used as the anode materials for sodium ion batteries which are considered to be one of the most potential large-scale energy storage systems. Herein, carbonyl groups and closed micropores are introduced into bamboo-derived hard carbon materials simultaneously to enhance the sodium ion storage performance. The carbonyl groups are demonstrated to enhance the reversible Na adsorption in the sloping region and closed micropores are beneficial to sodium ion storage in the low-voltage plat...

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