期刊论文

Adsorption characteristic of chromium(VI) on hydrotalcite,zeolite and diatomite inlquid-solid system

中文

中国粉体技术

1008-5548

2017

23

5

28-34

10.13732/j.issn.1008-5548.2017.05.006

(15K147,13K070):湖南省高校创新平台开放基金 (2015SK20043):湖南省重点研发计划项目 (YB2015B031):湖南省优秀博士学位论文获得者科研项目 (湘财建指[2014]287号):湖南省环境保护科技计划项目 (2015YJ041):中南林业科技大学引进***人才科研启动基金 (2310006):湖南省环境科学重点学科建设基金

本校为第一机构

采用静态吸附实验研究水滑石、沸石、硅藻土对Cr(VI)的吸附特性及其差异性;利用扫描电镜(SEM)、能谱仪(EDS)、红外光谱仪(FTIR)分析理化特性及其与吸附特性之间的关系。结果表明:水滑石和硅藻土对于Cr(VI)的等温吸附特性符合Freundlich模型,沸石符合Langmuir模型;水滑石、沸石、硅藻土的最大吸附量q_m分别为8.62、12.57、6.32 mg·g~(-1),吸附动力学特性均符合伪二级动力学方程;3种吸附剂均为优惠吸附,均是自发的、吸热的、无序的;从理化特性来看,沸石具有最优吸附条件。

In order to systematically grasp the adsorption properties and the differences of hexavalent chromium on hydrotalcite, zeolite and diatomite, the static adsorption of hexavalent chromium by hydrotalcite, zeolite and diatomite were investigated. The physicochemial properties of the adsorbing materials were characterized by SEM, EDS and FTIR. The results show that the adsorption of hexavalent chromium on hydrotalcite and diatomite fits with Freundlich model. The adsorption on zeolite fits with Langmuir model. According to the Langmuir equation, t...