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Mn doping accelerates regeneration of Fe2+ in FeOOH and promotes efficient H2O2 activation for degradation of As(III)

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成果类型:
期刊论文
作者:
Li, Yanmei;Wang, Jing;Xiang, Ziyang;Yang, Junhui;Yin, Jinglin;...
通讯作者:
Wang, Wenlei(wenlei_wang@csuft.edu.cn)
作者机构:
[Wang, Wenlei; Li, Yanmei; Xiang, Ziyang; Yin, Jinglin; Yang, Junhui; Guo, Xin; Wang, Jing] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.
[Wang, Wenlei] Cent South Univ Forestry & Technol, Changsha 410004, Peoples R China.
通讯机构:
[Wenlei Wang] C
College of Science, Central South University of Forestry and Technology, Changsha 410004, China
语种:
英文
关键词:
Arsenic oxidation;Fenton reaction;FeOOH;H2O2 activation;Mn-FeOOH@CA
期刊:
Colloids and Surfaces A: Physicochemical and Engineering Aspects
ISSN:
0927-7757
年:
2022
卷:
655
页码:
130166
基金类别:
The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Grant Nos: 41977129 , 21607176 ), Hunan Huxiang Young Talents Support Program , China (No. 2020RC3044 ), Changsha Outstanding Innovative Youth Training Program (Grant No. kq1802011 ), the Natural Science Foundation of Hunan Province , China (Grant No. 2020JJ4136 , 2022JJ90020 ), the Research Foundation of Education Bureau of Hunan Province , China (Grant No. 16B274 ), and the Innovation Fund for Post-graduates of Central South University of Forestry and Technology (Grant No. CX20192023 ). The authors also thank the reviewers for their constructive comments and suggestions.
机构署名:
本校为第一机构
院系归属:
理学院
摘要:
In this study, a carbonized aerogel (CA) decorated with Mn-FeOOH hybrid nanoparticles was prepared and has been used as a better heterogeneous photo-Fenton catalyst. Mn doping accelerated the regeneration of Fe2+ and promoted the decomposition of H2O2 while producing many hydroxyl radicals (·OH), which solved the mass transfer problem in the traditional heterogeneous Fenton system. The amount of·OH in the Mn-FeOOH@CA/H2O2 system within 40 min was 2.4 times higher than that in the FeOOH@CA/H2O2 system, which further indicates that·OH was the ...

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