Adsorption experiments of Zn2+ and Cd2+ ions from aqueous solutions onto vermiculite were conducted to test the applicability of two basic functions derived for calculating the change in the Gibbs' free energy (ΔG0) and the chemical potential (Δμ) between the initial and equilibrium states in ion adsorption systems. The functions were deduced on the basis of the thermodynamic principle that the chemical potentials of the reactants and products of a physicochemical reaction should be equal in the equilibrium state and, consequently, the chang...