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On the photoluminescence of multi-sites Ce3+ in T-phase orthosilicate and energy transfer from Ce3+ to Tb3+

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成果类型:
期刊论文
作者:
Tong, Xubo;Zhang, Xinmin*;Wu, Luyi;Zhang, Hongzhi;Seo, Hyo Jin
通讯作者:
Zhang, Xinmin
作者机构:
[Wu, Luyi; Tong, Xubo; Zhang, Hongzhi; Zhang, Xinmin] Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Seo, Hyo Jin] Pukyong Natl Univ, Dept Phys, Busan 608737, South Korea.
[Seo, Hyo Jin] Pukyong Natl Univ, Interdisciplinary Program Biomed Mech & Elect Eng, Busan 608737, South Korea.
通讯机构:
[Zhang, Xinmin] C
Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Cerium compounds;Emission spectroscopy;Energy transfer;Excited states;Phosphors;Photoluminescence;Silicon;Solid state reactions;Absorption peaks;Crystallographic sites;Emission intensity;Emission spectrums;Excitation spectrum;Orthosilicate;Site occupation;Spectral region;Fluorine compounds
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2018
卷:
748
页码:
871-875
基金类别:
The project was sponsored by the Technology Program of Environmental Protection Department of Hunan (No. 2013-312 ).
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Ce3+, Tb3+ co-doped T-phase orthosilicate Ba1.2Ca0.8SiO4 phosphors were prepared by means of solid state reactions. The synthesized samples were investigated using XRD and PL emission and excitation spectra. The emission spectra for Ce3+ doped Ba1.2Ca0.8SiO4 phosphors show broad bands in the 320–550 nm spectral region. The excitation spectra exhibit several absorption peaks in the range of 250–400 nm. Both the emission and excitation spectra are dependent on the excitation or monitoring wavelengths. We attribute these results to Ce3+ ions occ...

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