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Structural design on microporous cellulose-derived carbon via freeze-drying and carbonization for enhancing energy storage performances

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成果类型:
期刊论文
作者:
Li, Lei;Wu, Yiqiang;Jiang, Lili;Zhang, Zhen;Tian, Cuihua;...
通讯作者:
Yiqiang Wu<&wdkj&>Yan Qing
作者机构:
[Jiang, Lili] College of Furniture and Art Design, Central South University of Forestry and Technology, China
[Qing, Yan; Zhang, Zhen; Tian, Cuihua; Wu, Yiqiang; Jiang L.] College of Materials Science and Technology, Central South University of Forestry and Technology, China
通讯机构:
[Yiqiang Wu; Yan Qing] C
College of Materials Science and Technology, Central South University of Forestry and Technology, China
语种:
英文
关键词:
Biomass carbon;Cellulose nanofibrils;Electrode;Microporous structure;Supercapacitor
期刊:
Industrial Crops and Products
ISSN:
0926-6690
年:
2023
卷:
192
页码:
116097
基金类别:
This work was financially supported by National Natural Science Foundation of China ( 31890771 and 32201646 ), Young Elite Scientists Sponsorship Program from National Forestry and Grassland Administration of China ( 2019132614 ), Hunan Provincial Technical Innovation Platform and Talent Program in Science and Technology ( 2018RS3092 and 2018WK4028 ), and Outstanding Innovative Youth Training Program of Changsha ( KQ2009059 ).
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
家具与艺术设计学院
摘要:
Generating micropores of carbon electrode materials with pore sizes matching the size of transport ions plays a crucial role in improving the energy density of carbon-based supercapacitors. Herein, a biomass-derived carbon with a tailored three-dimensional (3D) porous structure was developed using TEMPO-oxidized cellulose nanofibrils (CNF). The specific surface area and micropore volume were controlled by fine-tuning via freeze-drying and carbonization-activation processes, yielding a carbonized CNF aerogel (CCA) with micropores dominant struct...

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