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Novel molecular imprinted polymers over magnetic mesoporous silica microspheres for selective and efficient determination of protocatechuic acid in Syzygium aromaticum

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成果类型:
期刊论文
作者:
Xie, Lianwu*;Guo, Junfang;Zhang, Yuping;Hu, Yunchu;You, Qingping;...
通讯作者:
Xie, Lianwu
作者机构:
[Hu, Yunchu; Xie, Lianwu] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Hunan, Peoples R China.
[Shi, Shuyun; Zhang, Yuping; Xie, Lianwu; Guo, Junfang; You, Qingping] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
通讯机构:
[Xie, Lianwu] C
Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
Magnetic microsphere;Mesoporous silica;Molecularly imprinted polymers;Protocatechuic acid;Syzygium aromaticum
期刊:
Food Chemistry
ISSN:
0308-8146
年:
2015
卷:
178
页码:
18-25
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21275163]; Science and Technology Program of Hunan Province, China [2012FJ2006, 2014RS4004]; Postdoctoral Science Foundation of ChinaChina Postdoctoral Science Foundation [2014M550426]; Postdoctoral Science Foundation of Central South University; Shenghua Yuying project of Central South University
机构署名:
本校为第一机构
院系归属:
理学院
摘要:
Improving sites accessibility can increase the binding efficiency of molecular imprinted polymers (MIPs). In this work, we firstly synthesized MIPs over magnetic mesoporous silica microspheres (Fe3O4@mSiO2@MIPs) for the selective recognition of protocatechuic acid (PCA). The resulting Fe3O4@mSiO2@MIPs were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectrometer (FT-IR), thermo-gravimetric analysis (TGA), Brunauer-Emmett-Teller (BET), and vibration sample magnetometer (VSM), and evaluated by adsorption isotherms/kinetics and competitive adsorption. The m...

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