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Single-phase white-emitting phosphors based on Eu2+-activated apatite-type Ba5(PO4)3Cl induced by (BO3)3− diadochic substitution

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成果类型:
期刊论文
作者:
Tao Zhao;Lu Xie;Fenzhong Long;Fangui Meng;Jin Han;...
通讯作者:
Fangui Meng<&wdkj&>Xinmin Zhang
作者机构:
[Tao Zhao; Lu Xie; Fenzhong Long; Fangui Meng; Jin Han; Xinmin Zhang] College of Materials and Energy, Central South University of Forestry and Technology, Changsha 410004, China
通讯机构:
[Fangui Meng; Xinmin Zhang] C
College of Materials and Energy, Central South University of Forestry and Technology, Changsha 410004, China
语种:
英文
期刊:
Chemical Physics
ISSN:
0301-0104
年:
2026
卷:
601
页码:
112936
机构署名:
本校为第一且通讯机构
摘要:
White-light emission with a single activator in a single host is an attractive function of phosphors. In this work, we investigated the photoluminescence properties of Ba 5 (PO 4 ) 3-x (BO 3 ) x Cl, which is a compound derived from apatite type Ba 5 (PO 4 ) 3 Cl by means of diadochic substitution, with Eu 2+ -activation using photoluminescence measurements. Phosphors show a tunable emission from deep blue to white and then orange under near ultraviolet light excitation. In the compound Ba 5 (PO 4 ) 3 Cl, Ba 2+ ions occupy two crystallographical...

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