High electrochemical stability of a 3D cross-linked network PEO@nano-SiO2 composite polymer electrolyte for lithium metal batterie

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成果类型：

期刊论文

作者：

Zhu, Yinghua;Cao, Jiang*;Chen, Hong;Yu, Qipeng;Li, Baohua*

通讯作者：

Cao, Jiang;Li, Baohua

作者机构：

[Li, Baohua; Yu, Qipeng; Cao, Jiang; Li, BH; Zhu, Yinghua] Tsinghua Univ, Grad Sch Shenzhen, Engn Lab Next Generat Power & Energy Storage Batt, Engn Lab Functionalized Carbon Mat, Shenzhen 518055, Peoples R China.

[Chen, Hong; Zhu, Yinghua] Cent South Univ Forestry & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.

[Chen, Hong] Foshan Univ, Sch Mat Sci & Energy Engn, Foshan 528000, Guangdong, Peoples R China.

[Cao, Jiang] Shenzhen Senior Technol Mat Co LTD, R&D Ctr, Shenzhen 518106, Peoples R China.

通讯机构：

[Cao, J; Li, BH] T

[Cao, Jiang] S

Tsinghua Univ, Grad Sch Shenzhen, Engn Lab Next Generat Power & Energy Storage Batt, Engn Lab Functionalized Carbon Mat, Shenzhen 518055, Peoples R China.

Shenzhen Senior Technol Mat Co LTD, R&D Ctr, Shenzhen 518106, Peoples R China.

语种：

英文

期刊：

Journal of Materials Chemistry A

ISSN：

2050-7488

年：

2019

卷：

期：

页码：

6832-6839

DOI：

10.1039/c9ta00560a

基金类别：

China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2017M620771]; National Nature Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51872157]; Shenzhen Technical Plan Project [JCYJ20170817161753629, KQJSCX20160226191136, JCYJ20170412170911187]; Guangdong Technical Plan Project [2015TX01N011]; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01N111]

机构署名：

本校为其他机构

院系归属：

材料科学与工程学院

摘要：

Polymer electrolytes have attracted great attention due to their promising abilities, however, only on further improving their safety and electrochemical performance can they be used as next generation electrolytes. Here, a novel composite polymer electrolyte (CPE) with nano-SiO2 acting as a cross-linking agent to form a 3D cross-linked network was synthesized to improve the electrochemical stability and mechanical ability. The novel CPE exhibited some excellent properties such as high ionic conductivity (4.65 × 10-3 S cm-1 at room temperature...

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High electrochemical stability of a 3D cross-linked network PEO@nano-SiO2 composite polymer electrolyte for lithium metal batterie

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