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Spectroscopic properties of red-emitting phosphor series (Y4-xEux)Zn4(SiO4)5 (x = 0.004–4) based on the site occupation of Eu3+ ion

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成果类型:
期刊论文
作者:
Tong, Xubo;Han, Jin;Zhang, Xinmin*
通讯作者:
Zhang, Xinmin
作者机构:
[Han, Jin; Tong, Xubo; Zhang, Xinmin] Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Hunan Prov Key Lab Mat Surface & Interface Sci &, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Zhang, Xinmin] C
Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Hunan Prov Key Lab Mat Surface & Interface Sci &, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Crystal atomic structure;Crystal symmetry;Emission spectroscopy;Europium compounds;Ions;Phosphors;Photoluminescence;Quenching;Silicates;X ray powder diffraction;Zinc compounds;Concentration dependence;Concentration quenching;Electric dipole transition;High temperature solid state methods;Magnetic dipole transition;Photo-luminescence excitation;Site symmetry;Spectroscopic property;Yttrium compounds
期刊:
Optical Materials
ISSN:
0925-3467
年:
2019
卷:
95
页码:
109236
基金类别:
The project was sponsored by the Technology Program of Environmental Protection Department of Hunan (No. 2013-312 ).
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Y4Zn4(SiO4)5 silicate doped with Eu3+ ions was prepared by the high temperature solid state method. The phase purity of phosphor series (Y4-xEux)Zn4(SiO4)5 (0.004 ≤ x ≤ 4) was checked by X-ray diffraction. The crystal structure, interatomic distances, and atom coordination numbers of Eu4Zn4(SiO4)5 were determined using x-ray powder diffraction. A study of the luminescent properties of (Y4-xEux)Zn4(SiO4)5 was carried out employing photoluminescence excitation and emission spectra and luminescence decay. The occupied sites of Eu3+ ions, relativ...

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