期刊论文

Research, advancement and prospect of molecularly imprinted polymers for organophosphorus pesticide residues

中文

农药学学报

1008-7303

2018

20

6

689-703

10.16801/j.issn.1008-7303.2018.0088

国家自然科学基金(21605046) 湖南省自然科学基金(2018JJ2671) 人社部留学回归人员择优资助项目(2016-176)。

本校为第一机构

为解决有机磷农药在土壤及水体中的残留污染问题,分子印迹技术在该类农药残留检测中的应用研究已得到迅速发展。文章就有机磷农药分子印迹聚合物(molecularly imprinted polymers,MIPs)的研究背景、分子印迹技术基本原理及分类、计算化学在筛选优化虚拟模板及功能单体中的应用,以及有机磷农药残留MIPs的制备与应用研究等内容进行了综述。 MIPs因具有结构可预测、特异识别和应用普遍的特性,可广泛用于光学传感、化学传感、电化学传感、光电传感、质量敏感传感、仿生催化及样品前处理等众多领域。可通过Discovery Studio、HyperChem及Gaussian 3种分子模拟软件对(虚拟)模板、功能单体以及二者所形...

In order to fight the pollution caused by the organophosphorus pesticide residues in soil and water, the molecular imprinting technology has been widely applied in the detection of pesticide residues. The research background of organophosphorus pesticides molecularly imprinted polymers (MIPs), the basic principles and classification of molecular imprinting techniques, the application of computational chemistry in screening and optimizing virtual templates and functional monomers, the preparation and application of organophosphorus pesticides MIPs and other relative content were reviewed. Due t...