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MOFs-Based Photoelectrochemical Sensing Interface and Its Applications

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成果类型:
期刊论文
作者:
Zhou, Cunyin;Huang, Juan;Wang, Qiong;Tang, Hao;Hu, Yunchu;...
通讯作者:
Wang, Q
作者机构:
[Wang, Q; Hu, Yunchu; Zhou, Cunyin; Huang, Juan; Wang, Wenlei; Wang, Qiong; Tang, Hao] Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.
[Wang, Q; Wang, Qiong] Hunan Normal Univ, Coll Chem & Chem Engn, Key Lab Chem Biol & Tradit Chinese Med Res, Minist Educ, Changsha 410081, Peoples R China.
通讯机构:
[Wang, Q ] C
Cent South Univ Forestry & Technol, Coll Sci, Changsha 410004, Peoples R China.
Hunan Normal Univ, Coll Chem & Chem Engn, Key Lab Chem Biol & Tradit Chinese Med Res, Minist Educ, Changsha 410081, Peoples R China.
语种:
英文
关键词:
Key words MOFs-based materials;photoelectrochemical sensing interface;photoelectrochemical sensing analysis
关键词(中文):
MOFs基材料;光电化学传感界面;光电化学传感分析
期刊:
化学进展
ISSN:
1005-281X
年:
2024
卷:
36
期:
6
页码:
893-903
基金类别:
National Natural Science Foundation of China [41977129]; Hunan Provincial Natural Science Foundation of China [2022JJ90020]; Excellent Youth Funding of Hunan Provincial Education Department of China [22B0246]
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
Photoelectrochemical sensing analysis is a rapidly developing new analytical technology in recent years, and photoelectric active materials are the key to photoelectrochemical sensing detection. Metal-organic frameworks (MOFs) and their derivatives may be ideal carriers for the construction of photoelectrochemical sensing interfaces by dispersing photoelectrically active substances. Due to the "antenna effect" of organic ligands in MOFs, the metal clusters can be regarded as activated discrete semiconductor quantum dots, giving them photoelectric properties similar to those of semiconductors. ...
摘要(中文):
光电化学传感分析是近年来迅速发展的一种新型分析技术,光电化学传感界面中的光电活性材料是光电化学传感检测的关键。金属有机框架(MOFs)及其衍生物可能是分散光电活性物质构建光电化学传感界面的理想载体。因MOFs材料中有机配体的“天线效应”,金属簇可看作被活化的分立的半导体量子点,使其具有与半导体类似的光电特性。对MOFs材料进行碳基化合物、有机聚合物、贵金属纳米粒子、无机氧化物、量子点修饰,构建MOFs基光电化学传感界面,可以提高MOFs的导电性,促进光生电子-空穴的分离,从而提高光电转换效率。利用MOFs基光电化学传感界面对光电化学传感产生信号放大的作用,可实现对目标物...

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