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Synthesis of hydrophilic sulfur-doped carbon aerogel microspheres and their mechanism of efficient removal of Sb(III) from aqueous solution

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成果类型:
期刊论文
作者:
Zeng, Qingyuan;Li, Jiahao*;Dai, Luming;Zhang, Jiaxing;Zeng, Tianyu;...
通讯作者:
Li, Jiahao;Hou, HB
作者机构:
[Cheng, Rong; Li, Jiahao; Li, JH; Zeng, Qingyuan; Zhou, Min; Dai, Luming; Zhang, Jiaxing; Zeng, Tianyu; Chen, Jiaao; Hou, Haobo] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Hubei, Peoples R China.
[Li, Jiahao; Zeng, Tianyu; Hou, Haobo] Wuhan Univ, Zhaoqing Inst Resources & Environm Technol, Zhaoqing 526200, Guangdong, Peoples R China.
[Chen, Jiaao] Cent South Univ Forestry & Technol, Coll Landscape Architecture, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Li, JH; Hou, HB ] W
Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Hubei, Peoples R China.
语种:
英文
关键词:
Antimony;Hydrophilic carbon aerogel;Selective removal Adsorption;DFT calculations
期刊:
Separation and Purification Technology
ISSN:
1383-5866
年:
2024
卷:
329
基金类别:
National Key Research and Devel- opment Program of China [2022YFC3902705]
机构署名:
本校为其他机构
院系归属:
风景园林学院
摘要:
Antimony pollution is well recognized to induce cancer and deformity. By polymerization technique, a carbon aerogel microsphere (Ce@SCA) modified by Ce and S with micron size, well-developed pore structure, and large specific surface area was created. Ce@SCA exhibited the advantages of efficient selectivity and high adsorption capacity for Sb(III) in water. The highest adsorption capacity derived using the Sips isothermal model was 345.18 mg.g(-1), and the Sb (III) adsorption process was thermodynamically estimated as spontaneous, exothermic, and entropy-decreasing chemisorption. Meanwhile, Ce...

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